Ion transport in small-molecule electrolytes based on LiI/3-hydroxypropionitrile with high salt contents

Wang, H.X., Wang, Z.X., Li, H., Meng, Q.B., & Chen, L.Q. (2007) Ion transport in small-molecule electrolytes based on LiI/3-hydroxypropionitrile with high salt contents. Electrochimica Acta, 52(5), pp. 2039-2044.

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Abstract

Abnormal “polymer-in-salt” conduction behavior is observed in a solid electrolyte composed of lithium iodide (LiI) and 3-hydroxypropionitrile (HPN). Based on comprehensive investigations by X-ray diffraction (XRD) and Raman and infrared spectroscopy, this abnormal conduction behavior is attributed to the formation of new ionic associates [Lim +In−]· · ·N C (m> n) and the reinforced hydrogen bonding of I· · ·HO in the electrolyte at high LiI concentrations.

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ID Code: 58206
Item Type: Journal Article
Refereed: Yes
Keywords: “Polymer-in-salt”, electrolyte, LiI/3-hydroxypropionitrile, Small-molecule electrolyte, Hydrogen bonding, Ionic associates
DOI: 10.1016/j.electacta.2006.08.013
ISSN: 0013-4686
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Physical Chemistry not elsewhere classified (030699)
Australian and New Zealand Standard Research Classification > ENGINEERING (090000) > MATERIALS ENGINEERING (091200) > Materials Engineering not elsewhere classified (091299)
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2007 Elsevier Ltd. All rights reserved
Deposited On: 14 Mar 2013 23:07
Last Modified: 14 May 2016 21:41

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