Asymmetrically decorated, doped porous graphene as an effective membrane for hydrogen isotope separation
Hankel, Marlies, Jiao, Yan, Du, Aijun, Gray, Stephen K., & Smith, Sean C. (2012) Asymmetrically decorated, doped porous graphene as an effective membrane for hydrogen isotope separation. The Journal of Physical Chemistry C, 116(11), pp. 6672-6676.
We propose a new route to hydrogen isotope separation which exploits the quantum sieving effect in the context of transmission through asymmetrically decorated, doped porous graphenes. Selectivities of D2 over H2 as well as rate constants are calculated based on ab initio interaction potentials for passage through pure and nitrogen functionalized porous graphene. One-sided dressing of the membrane with metal provides the critical asymmetry needed for an energetically favorable pathway.
Impact and interest:
Citation counts are sourced monthly from and citation databases.
These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science® generally from 1980 onwards.
Citations counts from theindexing service can be viewed at the linked Google Scholar™ search.
|Item Type:||Journal Article|
|Divisions:||Current > QUT Faculties and Divisions > Science & Engineering Faculty|
|Copyright Owner:||© 2012 American Chemical Society|
|Deposited On:||20 May 2013 22:47|
|Last Modified:||22 May 2013 04:08|
Repository Staff Only: item control page