2,3-Dimethoxy-10-oxostrychnidinium 3-carboxybenzoate trihydrate: the 1:1 proton-transfer compound of brucine with isophthalic acid
Smith, Graham, Wermuth, Urs D., Young, David J., & White, Jonathan M. (2006) 2,3-Dimethoxy-10-oxostrychnidinium 3-carboxybenzoate trihydrate: the 1:1 proton-transfer compound of brucine with isophthalic acid. Acta Crystallographica. Section E: Structure Reports Online, 62(4), o1553-o1555.
Abstract
The structure of the title compound C23H27N2O4+ . C8 H5O4 . 3H2O, has been determined at 130 K. The hydrogenisophthalate anions and the water molecules (one of which is disordered over two approximately equal sites) associate through extensive hydrogen-bonding interactions, including those with the common undulating brucinium cation layer substructures, forming a three-dimensional framework structure.
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| ID Code: | 6061 |
|---|---|
| Item Type: | Journal Article |
| Keywords: | single crystal structure, brucine, proton, transfer compounds |
| DOI: | doi:10.1107/S1600536806010026 |
| ISSN: | 1600-5368 |
| Subjects: | Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606) |
| Divisions: | Past > QUT Faculties & Divisions > Faculty of Science and Technology |
| Copyright Owner: | Copyright 2006 International Union of Crystallography |
| Copyright Statement: | The definitive version is available at www.blackwell-synergy.com |
| Deposited On: | 07 Feb 2007 |
| Last Modified: | 29 Feb 2012 23:18 |
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