Infrared study of the adsorption of NO, NO2 and CO on Rh/Al2O3 catalysts
Anderson, James A., Millar, Graeme J., & Rochester, Colin H. (1990) Infrared study of the adsorption of NO, NO2 and CO on Rh/Al2O3 catalysts. Journal of the Chemical Society, Faraday Transactions, 86(3), pp. 571-576.
Infrared spectra of NO, NO2 and CO adsorbed on Rh/Al2O3 have been recorded in order to identify the role of surface Rh-NO+ species in the reactions of NO and CO on Rh surfaces. Rh-NO+ was generated by thermally activated adsorption of NO, adsorption of NO on oxidised Rh or by adsorption of NO2. The latter also gave adsorbed nitrate on both Rh and the alumina support. In the presence of CO, Rh-NO+ acted as a precursor of the Rh(CO)(NO) mixed surface complex of CO and NO.
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|Item Type:||Journal Article|
|Keywords:||infrared, catalyst, rhodium, three way catalytic convertor|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Catalysis and Mechanisms of Reactions (030601)|
|Divisions:||Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
|Copyright Owner:||Copyright 1990 Royal Society of Chemistry|
|Copyright Statement:||Restrictions on further re-use and further distribution|
|Deposited On:||21 Aug 2013 22:50|
|Last Modified:||21 Aug 2013 22:57|
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