The anodized crystalline WO3 nanoporous network with enhanced electrochromic properties

Ou, Jian Zhen, Balendhran, Sivacarendran, Field, Matthew R., McCulloch, Dougal G., Zoolfakar, Ahmad S., Rani, Rozina A., Zhuiykov, Serge, O'Mullane, Anthony P., & Kalantar-zadeh, Kourosh (2012) The anodized crystalline WO3 nanoporous network with enhanced electrochromic properties. Nanoscale, 4(19), pp. 5980-5988.

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We demonstrate that a three dimensional (3D) crystalline tungsten trioxide (WO3) nanoporous network, directly grown on a transparent conductive oxide (TCO) substrate, is a suitable working electrode material for high performance electrochromic devices. This nanostructure, with achievable thicknesses of up to 2 μm, is prepared at room temperature by the electrochemical anodization of a RF-sputtered tungsten film deposited on a fluoride doped tin oxide (FTO) conductive glass, under low applied anodic voltages and mild chemical dissolution conditions. For the crystalline nanoporous network with thicknesses ranging from 0.6 to 1 μm, impressive coloration efficiencies of up to 141.5 cm2 C−1 are achieved by applying a low coloration voltage of −0.25 V. It is also observed that there is no significant degradation of the electrochromic properties of the porous film after 2000 continuous coloration–bleaching cycles. The remarkable electrochromic characteristics of this crystalline and nanoporous WO3 are mainly ascribed to the combination of a large surface area, facilitating increased intercalation of protons, as well as excellent continuous and directional paths for charge transfer and proton migration in the highly crystalline material.

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ID Code: 64306
Item Type: Journal Article
Refereed: Yes
Additional Information: Prior to commencement at QUT
DOI: 10.1039/C2NR31203D
ISSN: 2040-3372
Divisions: Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2012 Royal Society of Chemistry
Deposited On: 19 Nov 2013 23:54
Last Modified: 29 Mar 2017 15:12

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