Mesoporous titania microspheres composed of exposed active faceted nanosheets and their catalytic activities for solvent-free synthesis of azoxybenzenes

Yang, Liuliu, Shi, Guodong, Ke, Xuebin, Shen, Ruwei, & Zhang, Lixiong (2014) Mesoporous titania microspheres composed of exposed active faceted nanosheets and their catalytic activities for solvent-free synthesis of azoxybenzenes. CrystEngComm, 16(9), pp. 1620-1624.

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Abstract

Mesoporous titania microspheres composed of nanosheets with exposed active facets were prepared by hydrothermal synthesis in the presence of hexafluorosilicic acid. They exhibited superior catalytic activity in the solvent-free synthesis of azoxybenzene by oxidation of aniline and could be used for 7 cycles with slight loss of activity.

Impact and interest:

2 citations in Scopus
2 citations in Web of Science®
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ID Code: 67145
Item Type: Journal Article
Refereed: Yes
Keywords: titania microsphere, nanosheet, solvent-free synthesis, azoxybenzene
DOI: 10.1039/C3CE42252F
ISSN: 1466-8033
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > MACROMOLECULAR AND MATERIALS CHEMISTRY (030300) > Chemical Characterisation of Materials (030301)
Australian and New Zealand Standard Research Classification > ENGINEERING (090000) > CHEMICAL ENGINEERING (090400) > Catalytic Process Engineering (090402)
Australian and New Zealand Standard Research Classification > ENGINEERING (090000) > MATERIALS ENGINEERING (091200) > Ceramics (091201)
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2014 The Royal Society of Chemistry
Deposited On: 11 Feb 2014 22:52
Last Modified: 11 Mar 2014 10:24

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