Direct Detection of a Persistent Carbonyloxyl Radical in the Gas Phase

Poad, B. L. J., Kirk, B. B., Hettiarachchi, P. I., Trevitt, A. J., Blanksby, S. J., & Clark, T. (2013) Direct Detection of a Persistent Carbonyloxyl Radical in the Gas Phase. Angewandte Chemie-International Edition, 52(35), pp. 9301-9304.

View at publisher

Abstract

Long lived: Carbonyloxyl radicals (RCO2 .) are reactive intermediates that play key roles in initiating polymerization reactions. This reactivity also makes their direct observation difficult. For the first time a persistent organic RCO2 . radical is detected in the gas phase, its extraordinary longevity is attributed to the high barrier towards fragmentation owing to the endothermicity of the decarboxylation products.

Grant Numbers

ARC/DP0986738, ARC/DP120102922, ARC/DE120100467

Impact and interest:

4 citations in Scopus
Search Google Scholar™
4 citations in Web of Science®

Citation counts are sourced monthly from Scopus and Web of Science® citation databases.

These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science® generally from 1980 onwards.

Citations counts from the Google Scholar™ indexing service can be viewed at the linked Google Scholar™ search.

Full-text downloads:

57 since deposited on 20 Mar 2014
11 in the past twelve months

Full-text downloads displays the total number of times this work’s files (e.g., a PDF) have been downloaded from QUT ePrints as well as the number of downloads in the previous 365 days. The count includes downloads for all files if a work has more than one.

ID Code: 68930
Item Type: Journal Article
Refereed: Yes
Keywords: carbonyloxyl radical, electron photodetachment, electrospray ionization, ion-trap mass spectrometry, radical anions, tandem mass-spectrometry, kinetic characteristics, dibenzoyl peroxides, aroyloxyl radicals, ions, photodecomposition, decarboxylation, decomposition, spectroscopy, benzoyloxyl, ARC
DOI: 10.1002/anie.201304316
ISSN: 1433-7851
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000)
Divisions: Current > QUT Faculties and Divisions > Science & Engineering Faculty
Funding:
Copyright Owner: Wiley
Deposited On: 20 Mar 2014 03:51
Last Modified: 18 Mar 2015 09:32

Export: EndNote | Dublin Core | BibTeX

Repository Staff Only: item control page