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Vibrational spectroscopy of the basic manganese, ferric and ferrous phosphate minerals: strunzite, ferristrunzite and ferrostrunzite

Frost, Ray L., Kloprogge, J. Theo, Martens, Wayde N., & Williams, Peter A. (2002) Vibrational spectroscopy of the basic manganese, ferric and ferrous phosphate minerals: strunzite, ferristrunzite and ferrostrunzite. Neues Jahrbuch fur Mineralogie, Monatschefte, 2002(11), pp. 481-496.

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Abstract

The Raman spectra of strunzite, ferristrunzite and ferrostrunzite have been obtained at 298 and 77K using a combination of a thermal stage and Raman microscopy. These spectra are compared with their infrared spectra. The vibrational spectra of the two minerals are different, in line with differences in crystal structure and composition. Some similarity in the Raman spectra of the hydroxyl-stretching region exists, particularly at 298K, but characteristic differences in the OH deformation regions are observed. Significant shifts in the position of the Raman bands are observed by obtaining the spectra at 77K. Differences are also observed in the phosphate stretching and deformation regions.

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ID Code: 6942
Item Type: Journal Article
Keywords: ferric, manganese, phosphate, thermal stage, liquid nitrogen temperature, Raman spectroscopy
DOI: 10.1127/0028-3649/2002/2002-0481
ISSN: 0028-3649
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Catalysis and Mechanisms of Reactions (030601)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2002 Schweizerbart
Copyright Statement: Reproduced in accordance with the copyright policy of the publisher.
Deposited On: 13 Apr 2007
Last Modified: 09 Jun 2010 22:39

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