ortho-Bromo(propa-1,2-dien-1-yl)arenes : substrates for domino reactions
Masters, Kye-Simeon, Wallesch, Manuela, & Bräse, Stefan (2011) ortho-Bromo(propa-1,2-dien-1-yl)arenes : substrates for domino reactions. The Journal of Organic Chemistry, 76(21), pp. 9060-9067.
o-Bromo(propa-1,2-dien-1-yl)arenes exhibit novel and orthogonal reactivity under Pd catalysis in the presence of secondary amines to form enamines (concerted Pd insertion, intramolecular carbopalladation, and terminative Buchwald–Hartwig coupling) and of amides to form indoles (addition, Buchwald–Hartwig cyclization, and loss of the acetyl group). The substrates for these reactions can be accessed in a reliable and highly selective two-step process from 2-bromoaryl bromides.
Impact and interest:
Citation counts are sourced monthly from and citation databases.
These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science® generally from 1980 onwards.
Citations counts from theindexing service can be viewed at the linked Google Scholar™ search.
|Item Type:||Journal Article|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > ORGANIC CHEMISTRY (030500) > Organic Chemical Synthesis (030503)|
|Divisions:||Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
|Copyright Owner:||Copyright 2011 American Chemical Society|
|Copyright Statement:||This article is freely available from the American Chemical Society website 12 months after the publication date. See links to publisher website in this record|
|Deposited On:||02 Apr 2014 23:02|
|Last Modified:||15 May 2014 06:26|
Repository Staff Only: item control page