An efficient synthesis of (±)-frondosin B using a Stille–Heck reaction sequence
Masters, Kye-Simeon & Flynn, Bernard L. (2010) An efficient synthesis of (±)-frondosin B using a Stille–Heck reaction sequence. Organic & Biomolecular Chemistry, 8(6), pp. 1290-1292.
A concise, convergent synthesis of (±)-frondosin B has been developed based on the application of a Stille–Heck reaction sequence of 2-chloro-5-methoxybenzo[b]furan-3-yl triflate and 2-(3-butenyl)-3-(trimethylstannyl)cyclohex-2-enone giving the racemic natural product in a 34% overall yield.
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|Item Type:||Journal Article|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > ORGANIC CHEMISTRY (030500) > Natural Products Chemistry (030502)
Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > ORGANIC CHEMISTRY (030500) > Organic Chemical Synthesis (030503)
|Divisions:||Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
|Copyright Owner:||Copyright 2010 Royal Society of Chemistry|
|Copyright Statement:||Reproduced by permission of The Royal Society of Chemistry, no further distribution permitted.|
|Deposited On:||03 Apr 2014 00:54|
|Last Modified:||29 May 2014 02:13|
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