Alternation of chemoselective control in Stille-Heck and Heck-Stille reaction sequences

Masters, Kye-Simeon & Flynn, Bernard L. (2009) Alternation of chemoselective control in Stille-Heck and Heck-Stille reaction sequences. Advanced Synthesis & Catalysis, 351(4), pp. 530-536.

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Abstract

Sequential and one-pot Stille–Heck and Heck–Stille reaction processes have been invoked to give divergent access to polycyclic ring systems. Both reaction conditions and substrate structure are important in determining the nature of the reaction products formed. The Heck–Stille reactions have involved a reversal of the usual Heck regioselectivity and both cine- and ipso-substitutions have been observed in the Stille reaction.

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8 citations in Scopus
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8 citations in Web of Science®

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24 since deposited on 09 Apr 2014
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ID Code: 69931
Item Type: Journal Article
Refereed: Yes
Keywords: Heck reaction, one-pot process, palladium coupling, Stille reaction
DOI: 10.1002/adsc.200800678
ISSN: 1615-4169
Divisions: Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2009 Wiley-VCH Verlag GmbH&Co. KGaA, Weinheim
Deposited On: 09 Apr 2014 03:11
Last Modified: 30 May 2014 17:11

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