The syntheses of C6CH2.– and the corresponding carbenoid cumulene C6CH2 in the gas phase
Dua, Suresh, Blanksby, Stephen J., & Bowie, John H. (1998) The syntheses of C6CH2.– and the corresponding carbenoid cumulene C6CH2 in the gas phase. Chemical Communications, 16, pp. 1767-1768.
The ion (C6CH2)(.-) is formed in the gas phase by the process -C=C-C=C-C=CH2OEt --> (C6CH2)(.-) + EtO., and charge stripping of the product radical anion yields the carbenoid neutral C6CH2; this can be either a singlet (the ground state), which is best represented as the carbene :C=C=C=C=C=C=CH2, or a triplet; the adiabatic electron affinity and the dipole moment of the carbenoid neutral are calculated to be 2.82 eV and 7.33 D respectively.
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|Item Type:||Journal Article|
|Keywords:||laboratory detection, interstellar clouds, circumstellar|
|Divisions:||Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
|Deposited On:||10 Apr 2014 02:34|
|Last Modified:||10 Apr 2014 02:35|
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