Dynamic Micromapping of CO2 Sorption in Coal

Radliński, Andrzej P., Busbridge, Tara L., Gray, Evan MacA., Blach, Tomasz P., Cheng, Gang, Melnichenko, Yuri B., Cookson, David J., Mastalerz, Maria, & Esterle, Joan (2009) Dynamic Micromapping of CO2 Sorption in Coal. Langmuir, 25(4), pp. 2385-2389.

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We have applied X-ray and neutron small-angle scattering techniques (SAXS, SANS, and USANS) to study the interaction between fluids and porous media in the particular case of subcritical CO2 sorption in coal. These techniques are demonstrated to give unique, pore-size-specific insights into the kinetics of CO2 sorption in a wide range of coal pores (nano to meso) and to provide data that may be used to determine the density of the sorbed CO2. We observed densification of the adsorbed CO2 by a factor up to five compared to the free fluid at the same (p, T) conditions. Our results indicate that details of CO2 sorption into coal pores differ greatly between different coals and depend on the amount of mineral matter dispersed in the coal matrix: a purely organic matrix absorbs more CO2 per unit volume than one containing mineral matter, but mineral matter markedly accelerates the sorption kinetics. Small pores are filled preferentially by the invading CO2 fluid and the apparent diffusion coefficients have been estimated to vary in the range from 5 × 10-7 cm2/min to more than 10-4 cm2/min, depending on the CO2 pressure and location on the sample.

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23 citations in Scopus
22 citations in Web of Science®
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ID Code: 70389
Item Type: Journal Article
Refereed: Yes
DOI: 10.1021/la801925k
ISSN: 1520-5827
Divisions: Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2009 American Chemical Society
Deposited On: 23 Apr 2014 06:07
Last Modified: 21 Jun 2017 00:01

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