Hydrogen evolution by a metal-free electrocatalyst

Zheng, Yao, Jiao, Yan, Zhu, Yihan, Li, Lu Hua, Han, Yu, Chen, Ying, Du, Aijun, Jaroniec, Mietek, & Qiao, Shi Zhang (2014) Hydrogen evolution by a metal-free electrocatalyst. Nature Communications, 5(3783).

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Electrocatalytic reduction of water to molecular hydrogen via the hydrogen evolution reaction may provide a sustainable energy supply for the future, but its commercial application is hampered by the use of precious platinum catalysts. All alternatives to platinum thus far are based on nonprecious metals, and, to our knowledge, there is no report about a catalyst for electrocatalytic hydrogen evolution beyond metals. Here we couple graphitic-carbon nitride with nitrogen-doped graphene to produce a metal-free hybrid catalyst, which shows an unexpected hydrogen evolution reaction activity with comparable overpotential and Tafel slope to some of well-developed metallic catalysts. Experimental observations in combination with density functional theory calculations reveal that its unusual electrocatalytic properties originate from an intrinsic chemical and electronic coupling that synergistically promotes the proton adsorption and reduction kinetics.

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357 citations in Web of Science®
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ID Code: 70605
Item Type: Journal Article
Refereed: Yes
Additional URLs:
DOI: 10.1038/ncomms4783
ISSN: 2041-1723 (online) 1083-8155 (print)
Divisions: Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2014 Nature Publishing Group
Copyright Statement: Author's Pre-print: author can archive pre-print (ie pre-refereeing)
Author's Post-print: subject to Restrictions below, author can archive post-print (ie final draft post-refereeing)
Restrictions: •6 months embargo

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Deposited On: 29 Apr 2014 23:29
Last Modified: 21 Jun 2017 02:01

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