The lowest singlet and triplet states of the oxyallyl diradical
Ichino, T., Villano, S.M., Gianola, A.J., Goebbert, D.J., Sanov, A., Velarde, L., Blanksby, S.J., Zhou, X., Hrovat, D.A., Borden, W.T., & Carl Lineberger, W. (2009) The lowest singlet and triplet states of the oxyallyl diradical. Angewandte Chemie (International Edition), 48(45), pp. 8509-8511.
Small S-T splitting : The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55 ± 2) meV in adiabatic energy.
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|Item Type:||Journal Article|
|Additional Information:||Cited By (since 1996):32
Export Date: 18 March 2014
|Keywords:||Oxyallyl compounds, Photoelectron spectroscopy, Radicals, Reactive intermediates|
|Deposited On:||29 Apr 2014 04:30|
|Last Modified:||25 Jun 2014 07:10|
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