The lowest singlet and triplet states of the oxyallyl diradical

Ichino, T., Villano, S.M., Gianola, A.J., Goebbert, D.J., Sanov, A., Velarde, L., Blanksby, S.J., Zhou, X., Hrovat, D.A., Borden, W.T., & Carl Lineberger, W. (2009) The lowest singlet and triplet states of the oxyallyl diradical. Angewandte Chemie (International Edition), 48(45), pp. 8509-8511.

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Small S-T splitting : The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55 ± 2) meV in adiabatic energy.

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ID Code: 70682
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By (since 1996):32
Export Date: 18 March 2014
Source: Scopus
Keywords: Oxyallyl compounds, Photoelectron spectroscopy, Radicals, Reactive intermediates
DOI: 10.1002/anie.200904417
ISSN: 1433-7851
Deposited On: 29 Apr 2014 04:30
Last Modified: 25 Jun 2014 07:10

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