Poly-[μ-aqua-μ5-[(2,3,6-trichlorophenyl)acetato)-caesium]

Smith, Graham (2013) Poly-[μ-aqua-μ5-[(2,3,6-trichlorophenyl)acetato)-caesium]. Acta Crystallographica Section E : Structure Reports Online, 69(12), m628-m628.

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Abstract

In the structure of the title complex [Cs(C8H4Cl3O2)(H2O)]n, the Cs salt of the commercial herbicide fenac [(2,3,6-trichlorophenyl)acetic acid], the irregular eight-coordination about Cs+ comprises a bidentate chelate (O:Cl) interaction involving a carboxyl O-atom and an ortho-related ring substituted Cl atom which is also bridging, a triple-bridging carboxyl O-atom and a bridging water molecule. A two-dimensional sheet polymer is generated, lying parallel to (100), within which there are water O---H...O(carboxyl) hydrogen-bonding interactions.

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ID Code: 70886
Item Type: Journal Article
Refereed: Yes
Keywords: crystal structure, caesium, coordination polymer, hydrogen bonding, fenac
DOI: 10.1107/S1600536813029395
ISSN: 1600-5368
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2013 International Union of Crystallography
Copyright Statement: This open-access article is distributed under the terms of the Creative Commons Attribution Licence
http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and
reproduction in any medium, provided the original authors and source are cited.
Deposited On: 02 May 2014 02:21
Last Modified: 05 May 2014 00:57

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