Smith, Graham (2013) Poly[μ-aqua-aqua-μ5-(4-nitrobenzoato)-caesium]. Acta Crystallographica Section E : Structure Reports Online, 69(12), m664-m665.
In the structure of the title complex [Cs(C7H4N2O2)(H2O)2]n, the Cs salt of 4-nitrobenzoic acid, the irregular CsO9 coordination sphere comprises three bridging nitro O-donors, a bidentate carboxyl (O,O')-chelate interaction, a triple-bridging water molecule and a monodentate water molecule. A three-dimensional framework polymer is generated, within which there are water O-H...Ocarboxyl and water O-H...O(water) hydrogen-bonding interactions.
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|Item Type:||Journal Article|
|Keywords:||crystal structure, caesium, 4-nitrobenzoic acid , coordination polymer, hydrogen bonding|
|Divisions:||Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
|Copyright Owner:||Copyright 2013 International Union of Crystallography|
|Copyright Statement:||This open-access article is distributed under the terms of the Creative Commons Attribution Licence
http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and
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|Deposited On:||02 May 2014 03:17|
|Last Modified:||05 May 2014 01:00|
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