Smith, Graham (2013) Poly[μ-aqua-aqua-μ5-(4-nitrobenzoato)-caesium]. Acta Crystallographica Section E : Structure Reports Online, 69(12), m664-m665.

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In the structure of the title complex [Cs(C7H4N2O2)(H2O)2]n, the Cs salt of 4-nitrobenzoic acid, the irregular CsO9 coordination sphere comprises three bridging nitro O-donors, a bidentate carboxyl (O,O')-chelate interaction, a triple-bridging water molecule and a monodentate water molecule. A three-dimensional framework polymer is generated, within which there are water O-H...Ocarboxyl and water O-H...O(water) hydrogen-bonding interactions.

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ID Code: 70888
Item Type: Journal Article
Refereed: Yes
Keywords: crystal structure, caesium, 4-nitrobenzoic acid , coordination polymer, hydrogen bonding
DOI: 10.1107/S1600536813030638
ISSN: 1600-5368
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2013 International Union of Crystallography
Copyright Statement: This open-access article is distributed under the terms of the Creative Commons Attribution Licence
http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and
reproduction in any medium, provided the original authors and source are cited.
Deposited On: 02 May 2014 03:17
Last Modified: 05 May 2014 01:00

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