Poly[mu5-{hydrogen bis[(E)-cinnamato]}-caesium

Smith, Graham (2014) Poly[mu5-{hydrogen bis[(E)-cinnamato]}-caesium. Acta Crystallographica. Section E: Structure Reports Online, 70(2), m43-m44.

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In the structure of the title polymeric complex [Cs2(C9H7O2)(C9H8O2)]n, the Cs salt-adduct of trans-cinnamic acid, the Cs+ ions of the two individual irregular CsO8 coordination polyhedra lie on a twofold rotation axis and are linked by four bridging carboxyl O-donors from the two cinnamate ligand species. These two ligand components are inter-linked through a delocalized H atom within a short O...H...O hydrogen bond. Structure extension gives a two-dimensional coordination polymer which lies parallel to (001). The crystal was determined from a crystal twinned by non-merohedry, with a twin component ratio of approximately 1:1.

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ID Code: 70898
Item Type: Journal Article
Refereed: Yes
Keywords: crystal structure, caesium, coordination polymer, trans-cinnamic acid, twinned structure
DOI: 10.1107/S1600536814000804
ISSN: 1600-5368
Divisions: Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2014 The author
Copyright Statement: This open-access article is distributed under the terms of the Creative Commons Attribution Licence http://creativecommons.org/licenses/by/2.0/uk/legalcode, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Deposited On: 02 May 2014 02:28
Last Modified: 17 May 2014 08:14

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