Generation of three isomers of C7H- in the gas phase. A joint experimental and theoretical study
Dua, S., Bowie, J. H., & Blanksby, Stephen J. (1999) Generation of three isomers of C7H- in the gas phase. A joint experimental and theoretical study. European Journal of Mass Spectrometry, 5(5), pp. 309-317.
Three anion isomers of formula C7H have been synthesised in the mass spectrometer by unequivocal routes. The structures of the isomers are [HCCC(C-2)(2)](-), C6CH- and C2CHC4-. One of these, [HCCC(C-2)(2)](-), is formed in sufficient yield to allow it to be charge stripped to the corresponding neutral radical.
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|Item Type:||Journal Article|
|Keywords:||circumstellar molecules, three isomers of C7H-, neutral HC2C(C-2)(2), correlated molecular calculations, collision-induced dissociations, reionization mass-spectrometry, gaussian-basis sets, ab-initio mo, laboratory detection, interstellar molecule, neutral molecules, radical-anions, negative-ions|
|ISSN:||1751-6838 (online) 1469-0667 (print) 1356-1049|
|Divisions:||Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
|Copyright Owner:||Copyright © IM Publications 1999.|
|Deposited On:||26 May 2014 01:04|
|Last Modified:||05 Jan 2016 04:20|
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