Generation of three isomers of C7H- in the gas phase. A joint experimental and theoretical study

Dua, S., Bowie, J. H., & Blanksby, Stephen J. (1999) Generation of three isomers of C7H- in the gas phase. A joint experimental and theoretical study. European Journal of Mass Spectrometry, 5(5), pp. 309-317.

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Abstract

Three anion isomers of formula C7H have been synthesised in the mass spectrometer by unequivocal routes. The structures of the isomers are [HCCC(C-2)(2)](-), C6CH- and C2CHC4-. One of these, [HCCC(C-2)(2)](-), is formed in sufficient yield to allow it to be charge stripped to the corresponding neutral radical.

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ID Code: 71932
Item Type: Journal Article
Refereed: Yes
Additional URLs:
Keywords: circumstellar molecules, three isomers of C7H-, neutral HC2C(C-2)(2), correlated molecular calculations, collision-induced dissociations, reionization mass-spectrometry, gaussian-basis sets, ab-initio mo, laboratory detection, interstellar molecule, neutral molecules, radical-anions, negative-ions
DOI: 10.1255/ejms.290
ISSN: 1751-6838 (online) 1469-0667 (print) 1356-1049
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright © IM Publications 1999.
Deposited On: 26 May 2014 01:04
Last Modified: 05 Jan 2016 04:20

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