ZnO layers for opto-electronic applications from solution-based and low-temperature processing of an organometallic precursor

Bao Foong, Thelese Ru, Singh, Samarendra Pratap, Sonar, Prashant, Ooi, Zi-En, Chan, Khai Leok, & Dodabalapur, Ananth (2012) ZnO layers for opto-electronic applications from solution-based and low-temperature processing of an organometallic precursor. Journal of Materials Chemistry, 22(39), pp. 20896-20901.

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As printed and flexible plastic electronic gadgets become increasingly viable today, there is a need to develop materials that suit the fabrication processes involved. Two desirable requirements are solution-processable active materials or precursors and low-temperature processability. In this article, we describe a straightforward method of depositing ZnO films by simple spin coating of an organometallic diethylzinc precursor solution and annealing the resulting film at low temperatures (≤200 °C) without involving any synthetic steps. By controlling the humidity in which annealing is conducted, we are able to adjust the intrinsic doping level and carrier concentration in diethylzinc-derived ZnO. Doped or conducting transport layers are greatly preferable to undoped layers as they enable low-resistance contacts and minimize the potential drops. This ability to controllably realize doped ZnO is a key feature of the fabrication process that we describe in this article. We employ field-effect measurements as a diagnostic tool to measure doping levels and mobilities in ZnO and demonstrate that doped ZnO with high charge carrier concentration is ideal for solar cell applications. Respectable power conversion efficiencies (up to 4.5%) are achieved in inverted solar cells that incorporate diethylzinc-derived ZnO films as the electron transport layer and organic blends as the active material. Extensions of this approach to grow ternary and quaternary films with organometallic precursor chemicals will enable solution based growth of a number of semiconductor films as well as a method to dope them.

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14 citations in Scopus
15 citations in Web of Science®
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ID Code: 75204
Item Type: Journal Article
Refereed: Yes
Keywords: Active material, Diagnostic tools, Diethylzinc precursor, Doped ZnO, Doping levels, Electron transport layers, Fabrication process, Field-effect, Flexible plastics, Intrinsic doping, Key feature, Low temperature processing, Low temperatures, Low-resistance contacts, Optoelectronic applications, Organometallic precursors, Potential drop, Power conversion efficiencies, Processability, Semiconductor films, Solar-cell applications, Straight-forward method, Transport layers, Undoped layers, ZnO, ZnO films, ZnO layers, Carrier concentration, Conversion efficiency, Humidity control, Metallic films, Nanostructured materials, Organometallics, Semiconductor growth, Solar cells, Temperature, Zinc oxide, Semiconductor doping
DOI: 10.1039/c2jm34656g
ISSN: 0959-9428
Divisions: Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2012 The Royal Society of Chemistry
Deposited On: 02 Oct 2014 22:53
Last Modified: 22 Jun 2017 08:02

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