3D-hybrid networks with controllable electrical conductivity from the electrochemical deposition of terthiophene-functionalized polyphenylene dendrimers

John, Hermann, Bauer, Roland, Espindola, Pamela, Sonar, Prashant, Heinze, Jürgen, & Müllen, Klaus (2005) 3D-hybrid networks with controllable electrical conductivity from the electrochemical deposition of terthiophene-functionalized polyphenylene dendrimers. Angewandte Chemie - International Edition, 44(16), pp. 2447-2451.

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Abstract

(Figure Presented) Unusual conductivity effects: Suitably functionalized dendrimers (see picture) are capable of forming truly covalent three-dimensional networks with remarkably high conductivity on electrochemical doping. Depending on the charging level of the electroactive components used as building blocks for the dendrimer core and the perimeter, two separated regimes of electrical conductivity can be observed.

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36 citations in Web of Science®

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ID Code: 75219
Item Type: Journal Article
Refereed: Yes
Keywords: Conducting polymers, Cyclic voltammetry, Dendrimers, Networks, Polymers, Chemical bonds, Deposition, Doping (additives), Electric conductivity, Electrochemistry, Building blocks, Electrochemical doping, Perimeter, Three-dimensional networks
DOI: 10.1002/anie.200462378
ISSN: 1433-7851
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
Deposited On: 27 Oct 2014 22:51
Last Modified: 29 Oct 2014 04:07

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