Relation between charge carrier mobility and lifetime in organic photovoltaics

Vijila, C., Singh, S. P., Williams, E., Sonar, P., Pivrikas, A., Philippa, B., White, R., Naveen Kumar, E., Gomathy Sandhya, S., Gorelik, S., Hobley, J., Furube, A., Matsuzaki, H., & Katoh, R. (2013) Relation between charge carrier mobility and lifetime in organic photovoltaics. Journal of Applied Physics, 114(18).

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The relationship between charge carrier lifetime and mobility in a bulk heterojunction based organic solar cell, utilizing diketopyrrolopyrole- naphthalene co-polymer and PC71BM in the photoactive blend layer, is investigated using the photoinduced charge extraction by linearly increasing voltage technique. Light intensity, delay time, and temperature dependent experiments are used to quantify the charge carrier mobility and density as well as the temperature dependence of both. From the saturation of photoinduced current at high laser intensities, it is shown that Langevin-type bimolecular recombination is present in the studied system. The charge carrier lifetime, especially in Langevin systems, is discussed to be an ambiguous and unreliable parameter to determine the performance of organic solar cells, because of the dependence of charge carrier lifetime on charge carrier density, mobility, and type of recombination. It is revealed that the relation between charge mobility (μ) and lifetime (τ) is inversely proportional, where the μτ product is independent of temperature. The results indicate that in photovoltaic systems with Langevin type bimolecular recombination, the strategies to increase the charge lifetime might not be beneficial because of an accompanying reduction in charge carrier mobility. Instead, the focus on non-Langevin mechanisms of recombination is crucial, because this allows an increase in the charge extraction rate by improving the carrier lifetime, density, and mobility simultaneously. © 2013 AIP Publishing LLC.

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11 citations in Scopus
7 citations in Web of Science®
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ID Code: 75264
Item Type: Journal Article
Refereed: Yes
Keywords: Bimolecular recombination, High laser intensities, Organic photovoltaics, Photo-induced charge, Photoinduced currents, Photovoltaic systems, Temperature dependence, Temperature dependent, Carrier mobility, Extraction, Heterojunctions, Naphthalene, Photovoltaic cells, Solar cells, Carrier lifetime
DOI: 10.1063/1.4829456
ISSN: 00218979 (ISSN)
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2013 AIP Publishing
Deposited On: 21 Aug 2014 03:59
Last Modified: 24 Aug 2014 23:45

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