Surface plasmon-enhanced zeolite catalysis under light irradiation and its correlation with molecular polarity of reactants
Zhang, Xingguang, Du, Aijun, Zhu, Huaiyong, Jia, Jianfeng, Wang, Jun, & Ke, Xuebin (2014) Surface plasmon-enhanced zeolite catalysis under light irradiation and its correlation with molecular polarity of reactants. Chemical Communications, 50, pp. 13893-13895.
Enhanced catalytic performance of zeoltes via the plasmonic effect of gold nanoparticles has been discovered to be closely correlated with the molecular polarity of reactants. The intensified polarised electrostatic field of Na+ in NaY plays a critical role in stretching the C=O bond of aldehydes to improve the reaction rate.
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|Item Type:||Journal Article|
|Keywords:||Surface plasmon, zeolite, molecular polarity, acetalisation|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Catalysis and Mechanisms of Reactions (030601)
Australian and New Zealand Standard Research Classification > ENGINEERING (090000) > CHEMICAL ENGINEERING (090400) > Catalytic Process Engineering (090402)
Australian and New Zealand Standard Research Classification > TECHNOLOGY (100000) > NANOTECHNOLOGY (100700) > Nanomaterials (100708)
|Divisions:||Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
|Copyright Owner:||Copyright 2014 Royal Society of Chemistry|
|Deposited On:||27 Oct 2014 22:35|
|Last Modified:||18 Sep 2016 12:50|
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