Surface plasmon-enhanced zeolite catalysis under light irradiation and its correlation with molecular polarity of reactants

Zhang, Xingguang, Du, Aijun, Zhu, Huaiyong, Jia, Jianfeng, Wang, Jun, & Ke, Xuebin (2014) Surface plasmon-enhanced zeolite catalysis under light irradiation and its correlation with molecular polarity of reactants. Chemical Communications, 50, pp. 13893-13895.

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Abstract

Enhanced catalytic performance of zeoltes via the plasmonic effect of gold nanoparticles has been discovered to be closely correlated with the molecular polarity of reactants. The intensified polarised electrostatic field of Na+ in NaY plays a critical role in stretching the C=O bond of aldehydes to improve the reaction rate.

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ID Code: 78049
Item Type: Journal Article
Refereed: Yes
Keywords: Surface plasmon, zeolite, molecular polarity, acetalisation
DOI: 10.1039/C4CC03225J
ISSN: 1364-548X
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Catalysis and Mechanisms of Reactions (030601)
Australian and New Zealand Standard Research Classification > ENGINEERING (090000) > CHEMICAL ENGINEERING (090400) > Catalytic Process Engineering (090402)
Australian and New Zealand Standard Research Classification > TECHNOLOGY (100000) > NANOTECHNOLOGY (100700) > Nanomaterials (100708)
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2014 Royal Society of Chemistry
Deposited On: 27 Oct 2014 22:35
Last Modified: 18 Sep 2016 12:50

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