Graphene-type sheets of Nb1-xWxS2 : synthesis and in situ functionalization
Hoshyargar, Faegheh, Sahoo, Jugal Kishore, Tahir, Muhammad Nawaz, Yella, Aswani, Dietzsch, Michael, Natalio, Filipe, Branscheid, Robert, Kolb, Ute, Panthofer, Martin, & Tremel, Wolfgang (2013) Graphene-type sheets of Nb1-xWxS2 : synthesis and in situ functionalization. Dalton Transactions, 42(15), pp. 5292-5297.
Enlightened by the discovery of graphenes, a variety of inorganic analogues have been synthesized and characterized in recent years. Solvated Nb1-xWxS2 analogues of graphene-type sheets were prepared by lithiation and exfoliation of multistacked Nb1-xWxS2 coin roll nanowires (CRNWs), followed by in situ functionalization with gold nanoparticles to synthesize gold-loaded Nb1-xWxS2/Au nanocomposites. The Nb1-xWxS2 nanosheets and the corresponding Nb1-xWxS2/Au nanocomposites were characterized by high resolution electron microscopy (HRTEM), energy-dispersive X-ray spectroscopy (EDX), scanning transmission electron microscopy (STEM), dynamic light scattering (DLS) and scanning force microscopy (AFM). The graphene-type sheets are stable in water and other solvents and can be functionalized similarly as chalcogen-terminated surfaces (e.g. with Au nanoparticles).
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|Item Type:||Journal Article|
|Divisions:||Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
|Copyright Owner:||Copyright 2014 The Royal Society of Chemistry|
|Deposited On:||12 Dec 2014 00:03|
|Last Modified:||17 Dec 2014 04:38|
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