An infrared and Raman spectroscopic study of natural zinc phosphates
Frost, Ray L. (2004) An infrared and Raman spectroscopic study of natural zinc phosphates. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 60(7), pp. 1439-45.
Near infrared spectroscopy has been applied to a suite of hydrated hydroxylated phosphate minerals including cacoxenite, hureaulite, planerite, gormanite and wardite. The NIR spectra may be conveniently divided into three regions (a) the first hydroxyl fundamental (b) the water HOH overtone and (c) the region between 4000 and 4800 cm-1 where combination bands resulting from the bands in the mid-IR. For each of these regions, the minerals show distinctive spectra which enable their identification and characterisation. NIR spectroscopy is a less used technique which does have great application for the study of minerals, particularly minerals which have hydrogen in the structure either as hydroxyl units or as water bonded to the cation or as zeolitic water as is the case for cacoxenite. The study of minerals on planets is topical and NIR spectroscopy provides a rapid technique for the distinction and identification of minerals.
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|Item Type:||Journal Article|
|Keywords:||cacoxenite, hureaulite, planerite, gormanite, strengite, variscite, combination bands, difference bands, DRIFT, mid, infrared, near, infrared, Raman|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > INORGANIC CHEMISTRY (030200)|
|Divisions:||Past > QUT Faculties & Divisions > Faculty of Science and Technology|
|Copyright Owner:||Copyright 2004 Elsevier|
|Copyright Statement:||Reproduced in accordance with the copyright policy of the publisher: This journal is available online.|
|Deposited On:||15 Apr 2005|
|Last Modified:||29 Feb 2012 23:07|
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