Evolved gas analysis of coal-derived pyrite/marcasite

Cheng, Hongfei, Liu, Qinfu, Zhang, Shuai, Wang, Shaoqing, & Frost, Ray L. (2014) Evolved gas analysis of coal-derived pyrite/marcasite. Journal of Thermal Analysis and Calorimetry, 116(2), pp. 887-894.

View at publisher


The products evolved during the thermal decomposition of the coal-derived pyrite/marcasite were studied using simultaneous thermogravimetry coupled with Fourier-transform infrared spectroscopy and mass spectrometry (TG-FTIR–MS) technique. The main gases and volatile products released during the thermal decomposition of the coal-derived pyrite/marcasite are water (H2O), carbon dioxide (CO2), and sulfur dioxide (SO2). The results showed that the evolved products obtained were mainly divided into two processes: (1) the main evolved product H2O is mainly released at below 300 °C; (2) under the temperature of 450–650 °C, the main evolved products are SO2 and small amount of CO2. It is worth mentioning that SO3 was not observed as a product as no peak was observed in the m/z = 80 curve. The chemical substance SO2 is present as the main gaseous product in the thermal decomposition for the sample. The coal-derived pyrite/marcasite is different from mineral pyrite in thermal decomposition temperature. The mass spectrometric analysis results are in good agreement with the infrared spectroscopic analysis of the evolved gases. These results give the evidence on the thermal decomposition products and make all explanations have the sufficient evidence. Therefore, TG–MS–IR is a powerful tool for the investigation of gas evolution from the thermal decomposition of materials.

Impact and interest:

5 citations in Scopus
5 citations in Web of Science®
Search Google Scholar™

Citation counts are sourced monthly from Scopus and Web of Science® citation databases.

These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science® generally from 1980 onwards.

Citations counts from the Google Scholar™ indexing service can be viewed at the linked Google Scholar™ search.

Full-text downloads:

78 since deposited on 14 Apr 2015
37 in the past twelve months

Full-text downloads displays the total number of times this work’s files (e.g., a PDF) have been downloaded from QUT ePrints as well as the number of downloads in the previous 365 days. The count includes downloads for all files if a work has more than one.

ID Code: 83581
Item Type: Journal Article
Refereed: Yes
Keywords: Pyrite, Marcasite, Thermal decomposition, Evolved gas, Sulfur dioxide
DOI: 10.1007/s10973-013-3595-0
ISSN: 1588-2926
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Copyright Owner: Copyright 2014 Akademiai Kiado, Budapest, Hungary
Copyright Statement: Note: the archived file is an accepted manuscript, not the final published version of the paper, published version maybe viewed at pubisher's website: http://dx.doi.org/10.1007/s10973-013-3595-0
Deposited On: 14 Apr 2015 23:56
Last Modified: 17 Apr 2015 20:20

Export: EndNote | Dublin Core | BibTeX

Repository Staff Only: item control page