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Proton-transfer compounds of 8-Hydroxy-7-iodoquinoline-5-sulfonic aAcid (Ferron) with 4-Cholroaniline and 4-bromoaniline

Smith, Graham, Wermuth, Urs D., & Healy, Peter C. (2007) Proton-transfer compounds of 8-Hydroxy-7-iodoquinoline-5-sulfonic aAcid (Ferron) with 4-Cholroaniline and 4-bromoaniline. Acta Crystallographica. Section C: Crystal Structure Communications, C63(7), o405-o407.

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Abstract

Th crystal structures of the proton-transfer compounds of ferron (8-hydroxy-7-iodonaphthalene-5-sulfonic acid)with 4-chloroaniline and 4-bromoaniline, namely 4-chloroanilinium 8-hydroxy-7-iodonaphthalene-5-sulfonate monohydrate, C6H7ClN.C9H5INO4S- . H2O, and 4-bromanilinium 8-hydroxy-7-iodonaphthalene-5-sulfonate monohydrate, C6H7BrN.C9H5INO4S- . H2O, have been determined. The compounds are isomorphous and comprise sheets of hydrogen-bonded cations, anions and water moleculaes which are extended into a three-dimenional structure through centrosymmetric R22(10) O-H...N hydrogen-bonded ferron dimer interactions.

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ID Code: 8586
Item Type: Journal Article
Keywords: Crystal structure, proton, transfer compounds, ferron
DOI: 10.1107/S0108270107025772
ISSN: 0108-2701
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2007 International Union of Crystallography (IUCr)
Copyright Statement: The definitive version is available at www.blackwell-synergy.com
Deposited On: 12 Jul 2007
Last Modified: 29 Feb 2012 23:39

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