4-Chloroanilinium hydrogen (2R,3R)-tartrate monohydrate

Smith, Graham, Wermuth, D. Urs, & White, Jonathan M. (2007) 4-Chloroanilinium hydrogen (2R,3R)-tartrate monohydrate. Acta Crystallographica. Section E: Structure Reports Online, E63(Part 8), o3432-o3433.


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In the structure of the hydrated 1:1 compound of 4-chloroaniline with L-tartaric acid, C6H7ClN+ . C4H5O6- .H2O, determined at 130 K, the asymmetric unit comprises two 4-chloroanilinium cations, two hydrogen tartrate anions and two water molecules of solvation, and forms a two-dimensional duplex substructure comprising head-to-tail C1/1(7)hydrogen tartrate anions and water molecules. The pi-associated 4-chloroanilinium cation pairs [ring centroid separation = 3.5676(4) ang.; inter-ring dihedral angle = 0.5(1) deg.] are accommodatred within the channels of the substructure and are hydrogen-bonded to it peripherally.

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2 citations in Web of Science®
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ID Code: 8786
Item Type: Journal Article
Refereed: Yes
Keywords: crystal structure, L, tartrate
DOI: 10.1107/S1600536807032473
ISSN: 1600-5368
Subjects: Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606)
Divisions: Past > QUT Faculties & Divisions > Faculty of Science and Technology
Copyright Owner: Copyright 2007 International Union of Crystallography
Copyright Statement: Reproduced in accordance with the copyright policy of the publisher.
Deposited On: 26 Jul 2007 00:00
Last Modified: 29 Feb 2012 13:38

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