4-Chloroanilinium hydrogen (2R,3R)-tartrate monohydrate
Smith, Graham, Wermuth, D. Urs, & White, Jonathan M. (2007) 4-Chloroanilinium hydrogen (2R,3R)-tartrate monohydrate. Acta Crystallographica. Section E: Structure Reports Online, E63(Part 8), o3432-o3433.
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Abstract
In the structure of the hydrated 1:1 compound of 4-chloroaniline with L-tartaric acid, C6H7ClN+ . C4H5O6- .H2O, determined at 130 K, the asymmetric unit comprises two 4-chloroanilinium cations, two hydrogen tartrate anions and two water molecules of solvation, and forms a two-dimensional duplex substructure comprising head-to-tail C1/1(7)hydrogen tartrate anions and water molecules. The pi-associated 4-chloroanilinium cation pairs [ring centroid separation = 3.5676(4) ang.; inter-ring dihedral angle = 0.5(1) deg.] are accommodatred within the channels of the substructure and are hydrogen-bonded to it peripherally.
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| ID Code: | 8786 |
|---|---|
| Item Type: | Journal Article |
| Keywords: | crystal structure, L, tartrate |
| DOI: | 10.1107/S1600536807032473 |
| ISSN: | 1600-5368 |
| Subjects: | Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600) > Structural Chemistry and Spectroscopy (030606) |
| Divisions: | Past > QUT Faculties & Divisions > Faculty of Science and Technology |
| Copyright Owner: | Copyright 2007 International Union of Crystallography |
| Copyright Statement: | Reproduced in accordance with the copyright policy of the publisher. |
| Deposited On: | 26 Jul 2007 |
| Last Modified: | 29 Feb 2012 23:38 |
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