Vibrational spectroscopic study of hydrated uranyl oxide: curite
Raman and infrared spectra of the uranyl oxyhydroxide hydrate: curite is reported. Observed bands are attributed to the (UO2)2+ stretching and bending vibrations, U-OH bending vibrations, H2O and (OH)- stretching, bending and librational modes. U-O bond lengths in uranyls and O-H…O bond lengths are calculated from the wavenumbers assigned to the stretching vibrations. These bond lengths are close to the values inferred and/or predicted from the X-ray single crystal structure. The complex hydrogen-bonding network arrangement was proved in the structures of the curite minerals. This hydrogen bonding contributes to the stability of these uranyl minerals.
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