Alloying gold with copper makes for a highly selective visible-light photocatalyst for the reduction of nitroaromatics to anilines
Xiao, Qi, Sarina, Sarina, Waclawik, Eric R., Jia, Jianfeng, Chang, Jin, Riches, James D., Wu, Haishun, Zheng, Zhanfeng, & Zhu, Huaiyong (2016) Alloying gold with copper makes for a highly selective visible-light photocatalyst for the reduction of nitroaromatics to anilines. ACS Catalysis, 6(3), pp. 1744-1753.
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Finely control of product selectivity is an essential issue in organic chemical production. In the synthesis of functionalized anilines via reduction of the corresponding nitroarenes, the challenge is to selectively reduce only the nitro group in the presence of other reducible functional groups in nitroarene molecules at a high reaction rate. Normally, the nitroarene is reduced stepwise through a series of intermediates that remain as byproducts, increasing the aniline synthesis cost. Here we report that alloying small amounts of copper into gold nanoparticles can alter the reaction pathway of the catalytic reduction under visible-light irradiation at ambient temperature, allowing nitroaromatics to be transformed directly to anilines in a highly selective manner. The reasons for the high efficiency of the photocatalytic reduction under these comparatively benign conditions as well as the light-excited reaction mechanisms are discussed. This photocatalytic process avoids byproducts, exhibits a high reaction rate and excellent substituent tolerance, and can be used for the synthesis of many useful functionalized anilines under environmentally benign conditions. Switching of the reaction pathway simply by tailoring the bimetallic alloy NPs of the photocatalysts is effective for engineering of product chemoselectivity.
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|Item Type:||Journal Article|
|Keywords:||Au-Cu alloy, photocatalysis, reduction, reaction pathways, visible light|
|Subjects:||Australian and New Zealand Standard Research Classification > CHEMICAL SCIENCE (030000) > PHYSICAL CHEMISTRY (INCL. STRUCTURAL) (030600)|
|Divisions:||Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
|Copyright Owner:||Copyright 2016 American Chemical Society|
|Deposited On:||15 Mar 2016 01:54|
|Last Modified:||20 Mar 2016 04:32|
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