Cumyl phenyldithioacetate and 1-phenylethyl phenyldithioacetate: Versatile ambient-temperature RAFT agents

Barner-Kowollik, C. (2001) Cumyl phenyldithioacetate and 1-phenylethyl phenyldithioacetate: Versatile ambient-temperature RAFT agents. Australian Journal of Chemistry, 54(5).

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Cumyl phenyldithioacetate (CPDA) and 1-phenylethyl phenyldithioacetate (1-PEPDA) as versatile ambient-temperature reversible addition fragmentation chain transfer (RAFT) agents were presented. The synthesis of both the compounds was proceeded by subsequent reaction of the resulting phenyldithioacetic acid with stryene and benzyl chloride with carbon disulphide. The compunds were found to have relatively poor radical stablizing ability and were well suited for controling styrene and 1-PEPDA polymerization at ambient temperature.

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11 citations in Web of Science®

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ID Code: 99042
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :13 Export Date: 5 September 2016 CODEN: AJCHA Correspondence Address: Barner-Kowollik, C.; Ctr. for Adv. Macromolecular Design, Sch. of Chem. Eng. and Indust. Chem., University of New South Wales, Sydney, NSW 2052, Australia; email: References: Chong, Y.K., Le, T.P.T., Moad, G., Rizzardo, E., Thang, S.H., (1999) Macromolecules, 32, p. 2071; Rizzardo, E., Chiefari, J., Mayadunne, R.T.A., Moad, G., Thang, S.H., Synthesis of defined polymers by reversible addition fragmentation chain transfer: The RAFT process (2000) ACS Symp. Ser., 768; Quinn, J.F., Rizzardo, E., Davis, T.P., (2001) Chem. Commun., p. 1044; Barner-Kowollik, C., Quinn, J.F., Nguyen, T.L.U., Heuts, J.P.A., Davis, T.P., (2001) Macromolecules, 34, p. 7849; Quinn, J.F., Barner, L., Rizzardo, E., Davis, T.P., (2002) J. Polym. Sci. Chem., 40, p. 19; Barner, L., Zwaneveld, N., Heuts, J.P.A., Davis, T.P., unpublished resultsQuinn, J.F., Barner, L., Rizzardo, E., Davis, T.P., unpublished resultsUR -
Keywords: Agents, Free radical polymerization, Low temperature effects, Molecular weight, Styrene, Synthesis (chemical), Reversible addition fragmentation chain transfer (RAFT), Aromatic polymers
DOI: 10.1071/CH01149
ISSN: 00049425
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 22 Sep 2016 04:50

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