Reversible addition-fragmentation chain-transfer polymerization: Unambiguous end-group assignment via electrospray ionization mass spectrometry

Vana, P., Albertin, L., Barner, L., Davis, T. P., & Barner-Kowollik, C. (2002) Reversible addition-fragmentation chain-transfer polymerization: Unambiguous end-group assignment via electrospray ionization mass spectrometry. Journal of Polymer Science, Part A: Polymer Chemistry, 40(22).

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Abstract

Electrospray ionization mass spectrometry was performed to identify the structure of polymeric methyl acrylates generated via the cumyl dithiobenzoate (CDB), cumyl p-fluorodithiobenzoate (CPFDB), and 1-phenylethyl dithiobenzoate (PEDB) mediated reversible addition-fragmentation chain-transfer (RAFT) polymerizations. The relatively simple spectra clearly demonstrate the end groups of this living free-radical polymerization technique. Only polymeric chains carrying one leaving group of the RAFT agent and the dithiobenzoate end group as the active RAFT center were discovered. Multiple-stage mass spectrometric experiments and oxidation of the dithioester end group confirmed the structure of the generated polymers.

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ID Code: 99060
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :115
Export Date: 5 September 2016
CODEN: JPACE
Correspondence Address: Barner-Kowollik, C.; Ctr. for Adv. Macromolecular Design, Sch. of Chem. Eng. and Indust. Chem., The University of New South Wales, Sydney, NSW 2052, Australia; email: c.barner-kowollik@unsw.edu.au
References: Rizzardo, E., Chiefari, J., Mayadunne, R.T.A., Moad, G., Thang, S.H., (2000) Controlled/Living Radical Polymerization: Progress in ATRP, NMP, and RAFT, 768, pp. 278-296. , Matyjaszewski, K., Ed.; American Chemical Society: Washington, DC; Hawker, C.J., Bosman, A.W., Harth, E., (2001) Chem Rev, 101, p. 3661; Kamigaito, M., Ando, T., Sawamoto, M., (2001) Chem Rev, 101, p. 3689; Matyjaszewski, K., Xia, J., (2001) Chem Rev, 101, p. 2921; Stenzel-Rosenbaum, M., Davis, T.P., Chen, V., Fane, A.G., (2001) J Polym Sci Part A: Polym Chem, 2777, p. 39; Barner-Kowollik, C., Quinn, J.F., Morsley, D.R., Davis, T.P., (2001) J Polym Sci Part A: Polym Chem, 39, p. 1353; Barner-Kowollik, C., Quinn, J.F., Nguyen, T.L.U., Heuts, J.P.A., Davis, T.P., (2001) Macromolecules, 34, p. 7849; Barner-Kowollik, C., (2001) Aust J Chem, 54, p. 343; Barner-Kowollik, C., Vana, P., Quinn, J.F., Davis, T.P., (2002) J Polym Sci Part A: Polym Chem, 40, p. 1058; Monteiro, M.J., De Brouwer, H., (2001) Macromolecules, 34, p. 349; Monteiro, M.J., Hodgson, M., De Brouwer, H., (2000) J Polym Sci Part A: Polym Chem, 38, p. 3864; Goto, A., Sato, K., Tsujii, Y., Fukuda, T., Moad, G., Rizzardo, E., Thang, S.H., (2001) Macromolecules, 34, p. 402; Rodler, M., Harth, E., Rees, I., Hawker, C., (2000) J Polym Sci Part A: Polym Chem, 38, p. 4749; Ganachaud, F., Monteiro, M.J., Gilbert, R.J., Dourges, M.-A., Thang, S.H., Rizzardo, E., (2000) Macromolecules, 33, p. 6738; Barner-Kowollik, C., Vana, P., Davis, T.P., (2002) J Polym Sci Part A: Polym Chem, 40, p. 675; Nielen, M.W.F., (1999) Mass Spectrom Rev, 18, p. 309; Schriemer, D.C., Li, L., (1997) Anal Chem, 69, p. 4169; Hanton, S.D., (2001) Chem Rev, 101, p. 527; McEwen, C.N., Simonsick W.J., Jr., Larsen, B.S., Ute, K., Hatada, K., (1995) J Am Soc Mass Spectrom, 6, p. 906; Haddleton, D.M., Feeney, E., Buzy, A., Jasieczek, C.B., Jennings, K.R., (1996) Chem Commun, p. 1157; Stolarzewicz, A., Morejko-Buz, B., Neugebauer, D., (2000) Rapid Commun Mass Spectrom, 14, p. 2170; Saf, R., Hummel, K., (1997) Acta Polym, 48, p. 513; Jonscher, K.R., Yates, J.R., (1997) Anal Biochem, 244, p. 1; Oae, S., Yagihara, T., Okabe, T., (1972) Tetrahedron, 28, p. 3203; Buback, M., Kurz, C.H., Schmaltz, C., (1998) Macromol Chem Phys, 199, p. 1721; Bier, M.E., Schwartz, J.C., (1997) Electrospray Ionization Mass Spectrometry, p. 258. , Cole, R. B., Ed.; Wiley-Interscience: New York; Alper, H., Kwiatkowska, C., Petrignani, J.F., Sibtain, F., (1986) Tetrahedron Lett, 27, p. 5449; Buggle, K., Fallon, B., (1987) Monatsh Chem, 118, p. 1197; Carreta, F., Le Nocher, A.-M., Leriverend, C., Metzner, P., Pham, T.N., (1995) Bull Soc Chim Fr, 132, p. 67; Camilo, F.F., De Arruda Campos, I.P., Gruber, J., (1998) J Chem Res, p. 270; noteUR - https://www.scopus.com/inward/record.uri?eid=2-s2.0-0037112171&partnerID=40&md5=468d67046830be50f825e7f21bf9a086
Keywords: Electrospray ionization (ESI), Living polymerization, Mass spectrometry, Microstructure, Reversible addition-fragmentation chain transfer (RAFT), Crystal microstructure, Polymethyl methacrylates, Electrospray ionization mass spectrometry, Reversible addition fragmentation chain transfer, Free radical polymerization, polymerization
DOI: 10.1002/pola.10500
ISSN: 0887624X
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 22 Sep 2016 04:50

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