Influences of the structural design of RAFT agents on living radical polymerization kinetics

Davis, T. P., Barner-Kowollik, C., Nguyen, T. L. U., Stenzel, M. H., Quinn, J. F., & Vana, P. (2003) Influences of the structural design of RAFT agents on living radical polymerization kinetics. In Matyjaszewski, K. (Ed.) ACS Symposium Series.

Abstract

The influence of a p-substituent on the Z-group of cumyl dithiobenzoate (CDB) was investigated with respect to the rate retardation of CDB mediated RAFT polymerizations. The rate retardation is significantly decreased indicating the possible involvement of the p-position in a reversible termination reaction. CDB mediated copolymerizations of styrene and 2-hydroxyethyl methacrylate (HEMA) may indicate a change of the reactivity ratios when compared to conventional copolymerizations. The usage of macromolecular RAFT agents showed unexpected kinetic behavior, such as acceleration. © 2003 American Chemical Society.

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ID Code: 99070
Item Type: Book Chapter
Additional Information: Cited By :17
Export Date: 5 September 2016
CODEN: ACSMC
Correspondence Address: Davis, T. P.; Centre for Advanced Macromolecular Design, School of Chemical Engineering and Industrial Chemistry, University of New South Wales, Sydney, NSW 2052, Australia
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ISBN: 9780841238541
ISSN: 00976156
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 26 Sep 2016 05:00

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