Propagation and termination rate coefficients in N-vinylcarbazole free radical polymerization obtained via 440 nm pulsed laser and online 1H NMR kinetic experiments

Yin, M., Davis, T. P., Heuts, J. P. A., & Barner-Kowollik, C. (2003) Propagation and termination rate coefficients in N-vinylcarbazole free radical polymerization obtained via 440 nm pulsed laser and online 1H NMR kinetic experiments. Macromolecular Rapid Communications, 24(5-6).

View at publisher


Propagation rate coefficients, kp, of N-vinylcarbazole in solution have been determined via visible light pulsed-laser polymerization over a wide temperature range (EA = 25.3 ± 5 kJ · mol-1, A = 1.0 × 108 L · mol-1 · s-1). The kp data set was used to deduce (average) termination rate coefficients via 1H NMR spectroscopic kinetic experiments and the corresponding Arrhenius parameters(EA = -8.5 kJ · mol-1 ± 8 kJ · mol-1).

Impact and interest:

11 citations in Scopus
Search Google Scholar™
12 citations in Web of Science®

Citation counts are sourced monthly from Scopus and Web of Science® citation databases.

These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science® generally from 1980 onwards.

Citations counts from the Google Scholar™ indexing service can be viewed at the linked Google Scholar™ search.

ID Code: 99076
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :11
Export Date: 5 September 2016
Correspondence Address: Barner-Kowollik, C.; Ctr. for Adv. Macromolecular Design, Sch. of Chem. Eng./Indust. Chemistry, University of New South Wales, Sydney, NSW 2052, Australia; email:
References: Yin, M., Barner-Kowollik, C., Heuts, J.P.A., Davis, T.P., (2001) Macromol. Rapid Commun., 22, p. 1035; Buback, M., Gilbert, R.G., Hutchinson, R.A., Klumperman, B., Kuchta, F.-D., Manders, B.G., O'Driscoll, K.F., Schweer, J., (1995) Macromol. Chem. Phys., 196, p. 3267; Beuermann, S., Buback, M., Davis, T.P., Gilbert, R.G., Hutchinson, R.A., Olaj, O.F., Russell, G.T., Van Herk, A.M., (1997) Macromol. Chem. Phys., 198, p. 1545; Coote, M.L., Zammit, M.D., Davis, T.P., (1996) Trends Polym. Sci., 4, p. 189; Mastaka, M., Sadahito, M., Yamamoto, M., (1999) Polym. J., 10, p. 878; Hughes, J., North, A.M., (1966) Trans. Faraday Soc., 62, p. 1866; Zammit, M.D., Davis, T.P., Willett, G.D., (1997) Macromolecules, 30, p. 5655; Zammit, M.D., Davis, T.P., Rees, M.T.L., Russell, G.T., (1998) Macromolecules, 31, p. 1763; Buback, M., Busch, M., Lämmel, R., (1996) Macromol. Theory Simul., 5, p. 845; Van Hook, J.P., Tobolsky, A.V., (1958) J. Am. Chem. Soc., 80, p. 799; Buback, M., Huckestein, B., Kuchta, F.-D., Russell, G.T., Schmid, E., (1994) Macromol. Chem. Phys., 195, p. 2117; Buback, M., Kowollik, C., Wahl, A., (2000) Macromol. Chem. Phys., 201, p. 464
Keywords: Free radical polymerization, Kinetics (polym.), PLP-SEC, Propagation rate coefficients, Termination rate coefficients, Nuclear magnetic resonance spectroscopy, Pulsed laser applications, Rate constants, Rate coefficients, carbazole derivative, free radical, n vinylcarbazole, unclassified drug, article, chemical reaction kinetics, online analysis, polymerization, proton nuclear magnetic resonance, pulsed dye laser, temperature dependence
ISSN: 10221336
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 22 Sep 2016 04:50

Export: EndNote | Dublin Core | BibTeX

Repository Staff Only: item control page