Molecular composite materials formed from block copolymers containing a side-chain liquid crystalline segment and an amorphous styrene/maleic anhydride segment

Hao, X., Stenzel, M. H., Barner-Kowollik, C., Davis, T. P., & Evans, E. (2004) Molecular composite materials formed from block copolymers containing a side-chain liquid crystalline segment and an amorphous styrene/maleic anhydride segment. Polymer, 45(22).

View at publisher


Side-chain liquid crystalline block polymers containing a poly[6-[4-(4′-methoxyphenyl)phenoxy]hexyl methacrylate] (PMMA-LC) segment and a styrene-co-maleic anhydride segment (alternating structure) were prepared via reversible addition fragmentation chain transfer (RAFT) polymerization. PMMA-LC was initially prepared via RAFT polymerization mediated by 2-(2-cyanopropyl)dithiobenzoate (CPDB). The resulting polymer was subsequently isolated and used to re-initiate styrene/maleic anhydride alternating copolymerization. The block copolymerization proceeded to intermediate conversions with narrow polydispersities, however at higher conversions some molecular weight broadening was observed and this was attributed to radical-radical termination reactions. The resulting polymers were analyzed via size exclusion chromatography (SEC), differential scanning calorimetry (DSC) and polarizing optical microscopy (POM). Microporous honeycomb structured films were cast from solutions of the block copolymers to form porous molecular composites. © 2004 Elsevier Ltd. All rights reserved.

Impact and interest:

24 citations in Scopus
Search Google Scholar™
25 citations in Web of Science®

Citation counts are sourced monthly from Scopus and Web of Science® citation databases.

These databases contain citations from different subsets of available publications and different time periods and thus the citation count from each is usually different. Some works are not in either database and no count is displayed. Scopus includes citations from articles published in 1996 onwards, and Web of Science® generally from 1980 onwards.

Citations counts from the Google Scholar™ indexing service can be viewed at the linked Google Scholar™ search.

ID Code: 99089
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :24 Export Date: 5 September 2016 CODEN: POLMA Correspondence Address: Ctr. for Adv. Macromolecular Design, Sch. of Chem. Eng. and Indust. Chem., Univ. New S. Wales, Sydney, N.Australia; email: Chemicals/CAS: maleic anhydride, 108-31-6; styrene, 100-42-5 References: Paul, D.R., Newman, S., (1978) Polymer Blends, 1; Paul, D.R., Newman, S., (1978) Polymer Blends, 2; Utracki, L.A., (1991) Polym Networks Blends, 1, pp. 61-69; Adams, W.W., Helminiak, T.E., Viswanathan, A., Hwang, W.F., Wiff, D.R., (1982) Proc IUPAC Macromol Symp, 28, p. 828; Helminiak, T.E., Arnold, F.E., Benner, C.L., (1975) Polym Prepr (Am Chem Soc Div Polym Chem), 16, pp. 659-662; Hayakawa, T., Horiuchi, S., (2003) Angew Chem Int Ed, 42, pp. 2285-2289; Stenzel-Rosenbaum, M.H., Davis, T.P., Fane, A.G., Chen, V., (2001) Angew Chem Int Ed, 40, pp. 3428-3432; Barner-Kowollik, C., Dalton, H., Davis, T.P., Stenzel, M.H., (2003) Angew Chem Int Ed, 42, pp. 3664-3668; Finkelmann, H., Happ, M., Portugall, M., Ringsdorf, H., (1978) Makromol Chem, 179, pp. 2541-2544; Finkelmann, H., Day, D., (1979) Makromol Chem, 180, pp. 2269-2274; Duran, R., Strazielle, C., (1987) Macromolecules, 20, pp. 2853-2858; Silong, S., Lutfor, M.R., Rahman, M.Z.A., Yunus, W.M.Z.W., Haron, M.J., Ahmad, M.B., Yusoff, W.M.D.W., (2002) J Appl Polym Sci, 86, pp. 2653-2661; Li, M.-H., Keller, P., Grelet, E., Auroy, P., (2002) Macromol Chem Phys, 203, pp. 619-626; Nakano, T., Hasegawa, T., Okamoto, Y., (1993) Macromolecules, 26, pp. 5494-5502; Rodriguez-Parada, J.M., Percec, V., (1986) J Polym Sci Part A: Polym Chem, 24, pp. 1363-1378; Hao, X., Heuts, J.P.A., Barner-Kowollik, C., Davis, T.P., Evans, E., (2003) J Polym Sci Part A: Polym Chem, 41, pp. 2949-2963; Nieuwhof, R.P., Marcelis, A.T.M., Sudholter, E.J.R., (1997) Materials, Functionality and Design, Proceedings of the European Conference on Advanced Materials and Processes and Applications, 5th, Maastricht, Neth., Apr 21-23, 3; Mueller, B., Franze, K., Mebarek, D., (1995) Corrosion (Houston), 51, pp. 625-630; Kurbanova, R.A., Mirzaoglu, R., Kurbanov, S., Karatas, I., Pamuk, V., Ozcan, E., Okudan, A., Guler, E., (1997) J Adhes Sci Technol, 11, pp. 105-112; Ibn-Elhaj, M., Schadt, M., (2001) Nature (London, United Kingdom), 410, pp. 796-799; Adams, J., Gronski, W., (1989) Polym Prepr (Am Chem Soc Div Polym Chem), 30, pp. 446-447; Poser, S., Fischer, H., Arnold, M., (1996) J Polym Sci Part A: Polym Chem, 34, pp. 1733-1740; Fischer, H., Poser, S., Arnold, M., (1995) Macromolecules, 28, pp. 6957-6962; Wan, X., Tu, Y., Zhang, D., Zhou, Q., (2000) Polym Int, 49, pp. 243-247; Li, M.-H., Keller, P., Albouy, P.-A., (2003) Macromolecules, 36, pp. 2284-2292; Poser, S., Arnold, M., Fischer, H., (1996) Eur Polym J, 32, pp. 1169-1173; Hefft, M., Springer, J., (1990) Makromol Chem Rapid Commun, 11, pp. 397-401; Kreuder, W., Webster, O.W., (1986) Makromol Chem Rapid Commun, 7, pp. 5-13; Grubbs, R.H., Tumas, W., (1989) Science (Washington, DC, United States), 243, pp. 907-915; Komiya, Z., Pugh, C., Schrock, R.R., (1992) Macromolecules, 25, pp. 3609-3616; Percec, V., Lee, M.J., (1992) Macromol Sci Pure Appl Chem, 29, pp. 723-740; Adams, J., Tefehne, C.H., Gronski, W., (1994) Revue Roumaine de Chimie, 39, pp. 9-14; Galli, G., Chiellini, E., Laus, M., Angeloni, A.S., Bignozzi, M.C., Francescangeli, O., (1994) Mol Cryst Liq Cryst Sci Technol Sect A: Mol Cryst Liq Cryst, 254, pp. 429-443; Serhatli, I.E., Glli, G., Yagci, Y., Chiellini, E., (1995) Polym Bull (Berlin), 34, pp. 539-546; Walther, M., Finkelmann, H., (1996) Prog Polym Sci, 21, pp. 951-979; Poser, S., Fischer, H., Arnold, M., (1998) Prog Polym Sci, 23, pp. 1337-1379; Hahn, B., Wendorff, J.H., Portugall, M., Ringsdorf, H., (1981) Colloid Polym Sci, 259, pp. 875-884; Kodaira, T., Mori, K., (1992) Makromol Chem, 193, pp. 1331-1335; Komiya, Z., Schrock, R.R., (1993) Macromolecules, 26, pp. 1387-1392; Gomes, A.S., Carvalho, K., Spinto, M.R., (1995) Macromol Rapid Commun, 16, pp. 543-548; Gopalan, P., Li, X., Li, M., Ober, C.K., Gonzales, C.P., Hawker, C.J., (2003) J Polym Sci Part A: Polym Chem, 41, pp. 3640-3656; Lohmeijer, B.G.G., Schubert, U.S., (2004) J Polym Sci Part A: Polym Chem, 42, pp. 4016-4027; Zhang, H.-L., Chen, X., Wan, X., Zhou, Q.-F., Woo, E.M., (2003) Polym Int, 52, pp. 92-97; He, X., Zhang, H., Yan, D., Wang, X., (2003) J Polym Sci Part A: Polym Chem, 41, pp. 2854-2864; Chiefari, J., Chong, Y.K., Ercole, F., Krstina, J., Jeffery, J., Le T., P.T., Mayadunne, R.T.A., Thang, S.H., (1998) Macromolecules, 31, pp. 5559-5562; Barner, L., Barner-Kowollik, C., Davis, T.P., Stenzel, M.H., (2004) Aust J Chem, 57, p. 19; Szablan, Z., Ah Toy, A., Davis, T.P., Hao, X., Stenzel, M.H., Barner-Kowollik, C., (2004) J Polym Sci Part A: Polym Chem, 42, pp. 2432-2443; Donovan, M.S., Lowe, A.B., Sanford, T.A., McCormick, C.L., (2003) J Polym Sci Part A: Polym Chem, 41, pp. 1262-1281; Vana, P., Albertin, L., Barner, L., Davis, T.P., Barner-Kowollik, C., (2002) J Polym Sci Part A: Polym Chem, 40, pp. 4032-4037; Chernikova, E., Terpugova, P., Bui, C., Charleux, B., (2003) Polymer, 44, pp. 4101-4107; De Brouwer, H., Schellekens, M.A.J., Klumperman, B., Monteiro, M.J., German, A.L., (2000) J Polym Sci Part A: Polym Chem, 38, pp. 3596-3603; Barner, L., Barner-Kowollik, C., Davis, T.P., Stenzel, M.H., (2004) Aust J Chem, 57, pp. 19-24; Goto, A., Sato, K., Tsujii, Y., Fukuda, T., Moad, G., Rizzardo, E., Thang, S.H., (2001) Macromolecules, 34, pp. 402-408; Perrier, S., Davis, T.P., Carmichael, A.J., Haddleton, D.M., (2002) Chem Commun (Cambridge, United Kingdom), pp. 2226-2227; Montaudo, M.S., (2001) Macromolecules, 34, pp. 2792-2797; Barron, P.F., Hill, D.J.T., O'Donnell, J.H., O'Sullivan, P.W., (1984) Macromolecules, 17, pp. 1967-1972; You, Y.-Z., Hong, C.-Y., Pan, C.-Y., (2002) Eur Polym J, 38, pp. 1289-1295; Zhu, M.-Q., Wei, L.-H., Du, F.-S., Li, Z.-C., Li, F.-M., Li, M., Jiang, L., (2001) Chem Commun (Cambridge, United Kingdom), pp. 365-366; Widawski, G., Rawiso, M., Francois, B., (1994) Nature (London, United Kingdom), 369, pp. 387-389; Stenzel, M.H., (2002) Aust J Chem, 55, pp. 239-243; Yabu, H., Tanaka, M., Ijiro, K., Shimomura, M., (2003) Langmuir, 19, pp. 6297-6300; Stalmach, U., De Boer, B., Videlot, C., Van Hutten, P.F., Hadziioannou, G., (2000) J Am Chem Soc, 122, pp. 5464-5472; Stenzel, M.H., Davis, T.P., Fane, A.G., (2003) J Mater Chem, 13, pp. 2090-2097; Karthaus, O., Cieren, X., Maruyama, N., Shimomura, M., (1999) Mater Sci Eng C: Biomimet Supramol Syst, 10, pp. 103-106; Srinivasarao, M., Collings, D., Philips, A., Patel, S., (2001) Science (Washington, DC, United States), 292, pp. 79-82; Lord, H.T., Quinn, J.F., Angus, S.D., Whittaker, M.R., Stenzel, M.H., Davis, T.P., (2003) J Mater Chem, 13, pp. 2819-2824; Peng, J., Han, Y., Yang, Y., Li, B., (2004) Polymer, 45, pp. 447-452; Pitois, O., Francois, B., (1999) Eur Phys J B: Condens Matter Phys, 8, pp. 225-231; Karthaus, O., Maruyama, N., Cieren, X., Shimomura, M., Hasegawa, H., Hashimoto, T., (2000) Langmuir, 16, pp. 6071-6076; Angus, S.D., Davis, T.P., (2002) Langmuir, 18, pp. 9547-9553; Nakano, M., Deguchi, M., Matsumoto, K., Matsuoka, H., Yamaoka, H., (1999) Macromolecules, 32, pp. 7437-7443
Keywords: Honeycomb structured arrays, Liquid crystal, RAFT polymerization, Anhydrides, Polarizing optical microscopy (POM), Polydispersities, Size exclusion chromatography (SEC), Copolymerization, Differential scanning calorimetry, Honeycomb structures, Liquid crystal polymers, Molecular structure, Polymethyl methacrylates, Styrene, Copolymers, 2 (2 cyanopropyl)dithiobenzoate, acid anhydride, benzoic acid derivative, copolymer, maleic anhydride, poly[6 [4 (4' methoxyphenyl)phenoxy]hexylmethacrylate], polymer, radical, unclassified drug, addition reaction, article, chemical analysis, chemical reaction, chemical structure, composite material, dispersion, film, fragmentation reaction, gel permeation chromatography, isolation procedure, liquid, microscopy, molecular weight, molecule, polarizing optical microscopy, polymerization, porosity, reversible addition fragmentation chain transfer polymerization
DOI: 10.1016/j.polymer.2004.08.068
ISSN: 00323861
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 22 Sep 2016 04:50

Export: EndNote | Dublin Core | BibTeX

Repository Staff Only: item control page