Synthesis of various glycopolymer architectures via RAFT polymerization: From block copolymers to stars

Bernard, J., Hao, X., Davis, T. P., Barner-Kowollik, C., & Stenzel, M. H. (2006) Synthesis of various glycopolymer architectures via RAFT polymerization: From block copolymers to stars. Biomacromolecules, 7(1).

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Abstract

Well-defined linear poly(acryloyl glucosamine) (PAGA) exhibiting molar masses ranging from 3 to 120 K and low polydispersities have been prepared via reversible addition-fragmentation chain transfer polymerization (RAFT) in aqueous solution without recourse to protecting group chemistry. The livingness of the process was further demonstrated by successfully chain-extending one of these polymers with N-isopropylacrylamide affording narrow dispersed thermosensitive diblocks. This strategy of polymerization was finally extended to the preparation of glycopolymer stars from Z designed non-water-soluble trifunctional RAFT agent. After the growth of very short blocks of poly(hydroxyethyl acrylate) (DPnbranch = 10), AGA was polymerized in aqueous solution in a controlled manner affording well-defined 3-arm glycopolymer stars. © 2006 American Chemical Society.

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120 citations in Scopus
116 citations in Web of Science®
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ID Code: 99121
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :113
Export Date: 5 September 2016
CODEN: BOMAF
Correspondence Address: Stenzel, M.H.; Centre for Advanced Macromolecular Design, School of Engineering and Industrial Chemistry, University of New South Wales, Sydney, NSW 2052, Australia; email: camd@unsw.edu.au
Chemicals/CAS: poly(2 hydroxyethyl acrylate), 26022-14-0; poly(n isopropylacrylamide), 25189-55-3; polyacrylic acid, 74350-43-9, 87003-46-1, 9003-01-4, 9003-04-7; water, 7732-18-5; Acrylamides; N-isopropylacrylamide, 2210-25-5; Polymers
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Keywords: Agents, Glycols, Polyacrylates, Polymerization, Solutions, Synthesis (chemical), Glycopolymer architectures, Isopropylacrylamide, Polyacryloyl glucosamine (PAGA), Thermosensitive diblocks, Block copolymers, acrylic acid derivative, poly(2 hydroxyethyl acrylate), poly(acryloylglucosamine), poly(n isopropylacrylamide), polyacrylic acid, polymer, reagent, unclassified drug, water, aqueous solution, article, chemical structure, controlled study, dispersion, heat sensitivity, molecular weight, priority journal, process design, reversible addition fragmentation chain transfer polymerization, solubility, synthesis, Acrylamides, Glycosylation, Molecular Structure, Polymers, Temperature
DOI: 10.1021/bm0506086
ISSN: 15257797
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 30 Sep 2016 00:50

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