Design criteria for accurate measurement of bimolecular radical termination rate coefficients via the RAFT-CLD-T method

Johnston-Hall, G., Barner-Kowollik, C., & Monteiro, M. J. (2008) Design criteria for accurate measurement of bimolecular radical termination rate coefficients via the RAFT-CLD-T method. Macromolecular Theory and Simulations, 17(9).

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Abstract

The reversible addition-fragmentation chain transfer chain length dependent termination (RAFT-CLD-T) technique allows a simple experimental approach to obtain chain-lengthdependent termination rate coefficients as a function of conversion, kt i,i(x). This work provides a set of criteria by which accurate kt i,i (x) can be obtained using the RAFT-CLD-T method. Visualization of three-dimensional plots varying all kinetic rate parameters and starting concentrations demonstrates that only certain combinations give an accurate extraction of kt i,i (x). The current study provides hands-on guidelines for experimentalists applying the RAFT-CLD-T method. © 2008 WILEY-VCH Verlag GmbH & Co. KGaA.

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8 citations in Web of Science®
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ID Code: 99183
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :8
Export Date: 5 September 2016
CODEN: MTHSE
Correspondence Address: Barner-Kowollik, C.; Institut für Technische Chemie und Polymerchemie, Universität Karlsruhe (TH), Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76128 Karlsruhe, Germany; email: christopher.barner-kowollik@polymer.uni-karlsruhe.de
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Keywords: Kinetics (polym.), Living polymerization, Reversible addition fragmentation chain transfer (RAFT), Simulations, Termination, Chemical reactions, Free radical polymerization, Monomers, Polymerization, Polymers, Three dimensional, Accurate measurements, Chain length dependent terminations, Experimental approaches, Kinetic rate parameters, Reversible additions, Termination rate coefficients
DOI: 10.1002/mats.200800054
ISSN: 10221344
Divisions: Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 28 Jun 2017 15:01

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