Laser induced marking of polymer chains with radical spin traps

Junkers, T., Wong, E. H. H., Szablan, Z., Davis, T. P., Stenzel, M. H., & Barner-Kowollik, C. (2008) Laser induced marking of polymer chains with radical spin traps. Macromolecular Rapid Communications, 29(6).

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Abstract

A pathway for marking of polymer chains with radical spin traps during pulsed laser polymerization in free radical polymerization is presented. By introducing a so-called marker that forms a non-propagating radical at (or shortly after) the incidence of a laser pulse, a polymer subdistribution is generated by specifically terminating propagating radicals via combination with such a marker radical. The generated polymer subdistribution can subsequently be imaged by modern softionization mass spectrometry. Herein, the general methodology of the method in which such marker is generated via reaction of an initiating radical with a nitrone is demonstrated on the examples of BA and VAc. © 2008 WILEY-VCH Verlag GmbH & Co. KGaA.

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ID Code: 99187
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :8
Export Date: 5 September 2016
CODEN: MRCOE
Correspondence Address: Barner-Kowollik, C.; Centre for Advanced Macromolecular Design, School of Chemical Sciences and Engineering, University of New South Wales, Sydney, NSW 2052, Australia; email: c.barner-kowollik@unsw.edu.au
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Keywords: Electrospray ionization mass spectrometry, Propagation rate coefficient, Pulsed laser polymerization, Radical spin traps (polym.), ABS resins, Chemical reactions, Electrospray ionization, Free radicals, High performance liquid chromatography, Lasers, Mass spectrometers, Mass spectrometry, Monomers, Polymerization, Polymers, Pulsed laser applications, Rate constants, Spectrometers, Spectrometry, Spectrum analysis, Spin dynamics, Laser induced, Nitrone, Polymer chains, Pulsed lasers, Spin traps, Free radical polymerization
DOI: 10.1002/marc.200700820
ISSN: 10221336
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 10 Oct 2016 04:05

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