An atom-efficient conjugation approach to well-defined block copolymers using RAFT chemistry and hetero Diels-Alder cycloaddition

Sinnwell, S., Inglis, A. J., Davis, T. P., Stenzel, M. H., & Barner-Kowollik, C. (2008) An atom-efficient conjugation approach to well-defined block copolymers using RAFT chemistry and hetero Diels-Alder cycloaddition. Chemical Communications.

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Abstract

The tendency of electron-deficient dithioesters to undergo hetero Diels-Alder cycloadditions is successfully used to generate polymer conjugates between a RAFT-polymerized poly(styrene) and a diene-terminated poly(ε-caprolactone). © The Royal Society of Chemistry.

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ID Code: 99193
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :111
Export Date: 5 September 2016
CODEN: CHCOF
Correspondence Address: Stenzel, M. H.; Centre for Advanced Macromolecular Design (CAMD), School of Chemical Sciences and Engineering, University of New South Wales, Sydney, NSW 2052, Australia; email: m.stenzel@unsw.edu.au
Chemicals/CAS: polycaprolactone, 24980-41-4, 25248-42-4; polystyrene, 9003-53-6
References: Matyjaszewski, K., (2005) Prog. Polym. Sci., 30, pp. 858-875; Barner, L., Davis, T.P., Stenzel, M.H., Barner-Kowollik, C., (2007) Macromol. Rapid Commun., 28, pp. 539-559; Lutz, J.-F., (2007) Angew. Chem., Int. Ed., 46, pp. 1018-1025; Binder, W.H., Sachsenhofer, R., (2007) Macromol. Rapid Commun., 28, pp. 15-54; Fournier, D., Hoogenboom, R., Schubert, U.S., (2007) Chem. Soc. Rev., 36, pp. 1369-1380; Huisgen, R., Szeimies, G., Mobius, L., (1967) Chem. Ber., 100, pp. 2494-2507; Huisgen, R., (1968) Angew. Chem., Int. Ed. Engl., 7, pp. 321-328; Rostovtsev, V.V., Green, L.G., Fokin, V.V., Sharpless, K.B., (2002) Angew. Chem., Int. Ed., 41, pp. 2596-2599; Tornoe, C.W., Christensen, C., Meldal, M., (2002) J. Org. Chem., 67, pp. 3057-3064; Wu, P., Feldman, A.K., Nugent, A.K., Hawker, C.J., Scheel, A., Voit, B., Pyun, J., Fokin, V.V., (2004) Angew. Chem., Int. Ed., 43, pp. 3928-3932; Kolb, H.C., Finn, M.G., Sharpless, K.B., (2001) Angew. Chem., Int. Ed., 40, pp. 2004-2021; Durmaz, H., Dag, A., Altintas, O., Erdogan, T., Hizal, G., Tunca, U., (2007) Macromolecules, 40, pp. 191-198; Gacal, B., Durmaz, H., Tasdelen, M.A., Hizal, G., Tunca, U., Yagci, Y., Demirel, A.L., (2006) Macromolecules, 39, pp. 5330-5336; Kim, T.D., Luo, J.D., Tian, Y.Q., Ka, J.W., Tucker, N.M., Haller, M., Kang, J.W., Jen, A.K.Y., (2006) Macromolecules, 39, pp. 1676-1680; Quémener, D., Davis, T.P., Barner-Kowollik, C., Stenzel, M.H., (2006) Chem. Commun., pp. 5051-5053; Ting, S.R.S., Granville, A.M., Quémener, D., Davis, T.P., Stenzel, M.H., Barner-Kowollik, C., (2007) Aust. J. Chem., 60, pp. 405-409; Gao, H.F., Matyjaszewski, K., (2006) Macromolecules, 39, pp. 4960-4965; Laus, M., Papa, R., Sparnacci, K., Alberti, A., Benaglia, M., MacCiantelli, D., (2001) Macromolecules, 34, pp. 7269-7275; Alberti, A., Benaglia, M., Guerra, M., Gulea, M., Hapiot, P., Laus, M., MacCiantelli, D., Sparnacci, K., (2005) Macromolecules, 38, pp. 7610-7618; Heuze, B., Gasparova, R., Heras, M., Masson, S., (2000) Tetrahedron Lett., 41, pp. 7327-7331; Bastin, R., Albadri, H., Gaumont, A.-C., Gulea, M., (2006) Org. Lett., 8, pp. 1033-1036. , The full NMR data of 4, 5a, b and 6 are included in the ESI; Opsteen, J.A., Van Hest, J.C.M., (2005) Chem. Commun., pp. 57-59; Hoogenboom, R., Moore, B.C., Schubert, U.S., (2006) Chem. Commun., pp. 4010-4012. , A description of the experiment is included in the ESI A detailed peak assignment of the ESI-MS spectra of 4, 6 and 7 is included in the ESI
Keywords: copolymer, polycaprolactone, polystyrene, article, atom transfer radical polymerization, chemical structure, cycloaddition, Diels Alder reaction, electron transport, esterification, nonhuman, nuclear magnetic resonance spectroscopy, polymerization, reversible addition fragmentation chain transfer
DOI: 10.1039/b718180a
ISSN: 13597345
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 10 Oct 2016 04:48

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