Continuous ATRP synthesis of block-like copolymers via column reactors: Design and validation of a kinetic model

Dervaux, B., Junkers, T., Barner-Kowollik, C., & Du Prez, F. E. (2009) Continuous ATRP synthesis of block-like copolymers via column reactors: Design and validation of a kinetic model. Macromolecular Reaction Engineering, 3(9).

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Abstract

A model for the block-like copolymerization via continuous supported ATRP was developed, enabling the calculation of the sequence distributions of the different monomers as a function of chain length in continuous flow reactors. Polydispersity indices, copolymer compositions, and complete molecular weight distributions could be predicted. The model was extensively tested under a wide range of reaction conditions and the outcome was compared with experimental data. An almost perfect match between the simulated and experimental kinetic data (first order kinetic plots, conversions, and PDI) was observed. A reasonable fit for the composition data of the copolymers was obtained. The influence of the flow rate in the column reactor on the copolymer composition was studied. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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ID Code: 99208
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :11
Export Date: 5 September 2016
Correspondence Address: Du Prez, F.E.; Department of Organic Chemistry, Polymer Chemistry Research Group, Ghent University, Krijgslaan 281 (S4-bis), 9000 Ghent, Belgium; email: filip.duprez@ugent.be
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Keywords: Atom transfer radical polymerization (ATRP), Block-like copolymer, Continuous flow reactor, PREDICI®, Simulations, Column reactors, Composition data, Continuous flow reactors, Copolymer compositions, Experimental data, Experimental kinetics, First order kinetics, Kinetic models, Perfect matches, Polydispersity indices, Predici, Reaction conditions, Sequence distribution, Copolymerization, Copolymers, Free radical polymerization, Molecular weight distribution, Plastic products, Polydispersity, Synthesis (chemical), Atom transfer radical polymerization
DOI: 10.1002/mren.200900046
ISSN: 1862832X
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 09 Oct 2016 23:30

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