Mark-houwink parameters for the universal calibration of acrylate, methacrylate and vinyl acetate polymers determined by online size- exclusion chromatography - Mass spectrometry

Gruendling, T., Junkers, T., Guilhaus, M., & Barner-Kowollik, C. (2010) Mark-houwink parameters for the universal calibration of acrylate, methacrylate and vinyl acetate polymers determined by online size- exclusion chromatography - Mass spectrometry. Macromolecular Chemistry and Physics, 211(5).

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Abstract

Size exclusion chromatography coupled online to electrospray ionization mass spectrometry (SEC/ESI-MS) is employed to establish universal calibration (UC) relationships for a number of linear poly(alkyl acrylates) and poly(alkyl methacrylates) (pMMAs) as well as poly(vinyl acetate) synthesized via radical chain transfer polymerization. It is demonstrated that in the analyzed molecular weight range, Mark-Houwink-Kuhn-Sakurada (MHKS) coefficients can be successfully determined in relation to values of pMMA. The agreement between the UC model using mass spectrometry-derived MHKS coefficients and the measured data was generally better than 10%. The MHKS values reported herein are expected to remain valid up to 20 kDa. A comparison with the outcome of UC using literature reported MHKS coefficients determined by intrinsic viscosity-molecular weight (IV-MW) measurements is provided. Errors of more than 30% can result when these literature values are employed in the low molecular weight range (M̄n < 20 kDa). Use of MHKS coefficients derived from IV-MW measurements in UC is, therefore, strongly discouraged at molecular weights below 20 kDa. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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ID Code: 99239
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :23
Export Date: 5 September 2016
CODEN: MCHPE
Correspondence Address: Gruendling, T.; Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology(KIT), Engesserstr. 18, 76128 Karlsruhe, Germany
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Keywords: Chromatography, Electrospray ionization mass spectrometry (ESI-MS), Intrinsic viscosity molecular weight relationship, Mark-houwink-kuhn-sakurada (MHKS) coefficients, Size exclusion chromatography (SEC), Triple detection, Universal calibration, Viscosity, Electrospray ionization mass spectrometry, Intrinsic viscosity, Mark-Houwink, Acrylics, Alkylation, Calibration, Chromatographic analysis, Electrospray ionization, Gel permeation chromatography, Ionization, Mass spectrometers, Mass spectrometry, Molecular weight, Particle detectors, Polyvinyl acetates, Ultrasonics, Size exclusion chromatography
DOI: 10.1002/macp.200900323
ISSN: 10221352
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 06 Oct 2016 04:43

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