Reversible diels-alder chemistry as a modular polymeric color switch

Paulöhrl, T., Inglis, A. J., & Barner-Kowollik, C. (2010) Reversible diels-alder chemistry as a modular polymeric color switch. Advanced Materials, 22(25).

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(Figure Presented) A fully reversible polymeric color-switch system based on reversible Diels-Alder chemistry between cyclopentadienyl capped polymers and highly electron deficient dithioesters is described. The detailed reaction progress could be mapped on a molecular level for several complete switching cycles and was underpinned by an ESI-MS study. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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ID Code: 99254
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :30
Export Date: 5 September 2016
Correspondence Address: Paulöhrl, T.; Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76128 Karlsruhe, Germany
Chemicals/CAS: Cyclopentanes; Polymers; Cyclopentanes; Polymers
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Keywords: Cyclopentadienyls, Diels-Alder, Dithioesters, Electron-deficient, Molecular levels, Reaction progress, Switch systems, Switching cycles, Polymers, cyclopentane derivative, polymer, article, chemistry, color, electrospray mass spectrometry, ultraviolet spectrophotometry, Cyclopentanes, Spectrometry, Mass, Electrospray Ionization, Spectrophotometry, Ultraviolet
DOI: 10.1002/adma.201000361
ISSN: 09359648
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 07 Oct 2016 03:22

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