Star and miktoarm star block (co)polymers via self-assembly of ATRP generated polymer segments featuring Hamilton wedge and cyanuric acid binding motifs

Altintas, O., Tunca, U., & Barner-Kowollik, C. (2011) Star and miktoarm star block (co)polymers via self-assembly of ATRP generated polymer segments featuring Hamilton wedge and cyanuric acid binding motifs. Polymer Chemistry, 2(5).

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Hamilton wedge (HW) end-functionalized poly(styrene) (PS-HW, Mn = 5400 g mol-1, PDI = 1.06), HW mid-chain functionalized poly(styrene) (PS-HW-PS, Mn = 4600 g mol-1, PDI = 1.04), cyanuric acid (CA) end-functionalized poly(styrene) (PS-CA, Mn = 3700 g mol-1, PDI = 1.04) and CA end- functionalized poly(methyl methacrylate) (PMMA-CA, Mn = 8500 g mol-1, PDI = 1.13) precursors were successfully synthesized via a combination of atom transfer radical polymerization (ATRP) and copper catalyzed azide-alkyne cycloaddition (CuAAC). The precursor polymers were characterized via size exclusion chromatography (SEC) and 1H NMR with respect to both molecular weight and structure. Supramolecular homopolymer (PS-HW-PS-CA), block copolymer (PS-HWPMMA-CA), star polymer (PS-HW-PS - PS-CA) as well as miktoarm star polymer (PS-HW-PS - PMMA- CA) were formed in solution in high yields at ambient temperature (association close to 89% for PS-HW-PS-CA, 90% for PS-HW-PS - PS-CA and 98% for PS-HW-PS - PMMA-CA) via H-bonding between the orthogonal recognition units, HW and CA. The formation of supramolecular polymers was confirmed via 1H NMR at ambient temperature in deuterated methylene chloride (CD 2Cl2) solution. © The Royal Society of Chemistry 2011.

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ID Code: 99262
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :32 Export Date: 5 September 2016 Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Institut Für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76128 Karlsruhe, Germany; email: References: Roovers, J., (1998) Star and Hyperbranched Polymers, p. 285. , ed. M. Mishra and S. Kobayashi, Marcel Dekker, New York; Burchard, W., (1999) Adv. Polym. Sci., 143, pp. 113-194; Hadjichristidis, N., Pitsikalis, M., Pispas, S., Iatrou, H., (2001) Chem. Rev., 101, pp. 3747-3792; Hirao, A., Hayashi, M., Loykulnant, S., Sugiyama, K., Ryu, S.W., Haraguchi, N., Matsuo, A., Higashihara, T., (2005) Prog. Polym. Sci., 30, pp. 111-182; Chiefari, J., Chong, Y.K., Ercole, F., Krstina, J., Jeffery, J., Le, T.P.T., Mayadunne, R.T.A., Thang, S.H., (1998) Macromolecules, 31, pp. 5559-5562; Barner-Kowollik, C., Perrier, S., (2008) J. Polym. Sci., Part A: Polym. Chem., 46, pp. 5715-5723; Georges, M.K., Veregin, R.P.N., Kazmaier, P.M., Hamer, G.K., (1993) Macromolecules, 26, pp. 2987-2988; Hawker, J.C., Bosman, A.W., Harth, E., (2001) Chem. Rev., 101, pp. 3661-3688; Kato, M., Kamigaito, M., Sawamoto, M., Higashimura, T., (1995) Macromolecules, 28, pp. 1721-1723; Ouchi, M., Terashima, T., Sawamoto, M., (2009) Chem. Rev., 109, pp. 4963-5050; Wang, J.S., Matyjaszewski, K., (1995) Macromolecules, 28, pp. 7901-7910; Di Lena, F., Matyjaszewski, K., (2010) Prog. Polym. Sci., 35, pp. 959-1021; Percec, V., Barboiu, B., (1995) Macromolecules, 28, pp. 7970-7972; Rosen, B.M., Percec, V., (2009) Chem. Rev., 109, pp. 5069-5119; Matyjaszewski, K., Xia, J., (2001) Chem. Rev., 101, pp. 2921-2990; Barner, L., Davis, T.P., Stenzel, M.H., Barner-Kowollik, C., (2007) Macromol. Rapid Commun., 28, pp. 539-559; Sumerlin, B.S., Vogt, A.P., (2010) Macromolecules, 43, pp. 1-13; Iha, R.K., Wooley, K.L., Nystrom, A.M., Burke, D.J., Kade, M.J., Hawker, C.J., (2009) Chem. Rev., 109, pp. 5620-5686; Khanna, K., Varshney, S., Kakkar, A., (2010) Polym. Chem., 1, pp. 1171-1185; Barner-Kowollik, C., Du Prez, F.E., Espeel, P., Hawker, C.J., Junkers, T., Schlaad, H., Van Camp, W., (2011) Angew. Chem., Int. Ed., 50, pp. 60-62; Lehn, J.-M., (2007) Chem. Soc. Rev., 36, pp. 151-160; Krische, M.J., Lehn, J.-M., (2000) Struct. Bonding(Berlin, Ger.), 96, pp. 3-29; Beijer, F.H., Kooijman, H., Spek, A.L., Sijbesma, R.P., Meijer, E.W., (1998) Angew. Chem., Int. Ed., 37, pp. 75-78; Knapp, R., Schott, A., Rehahn, M., (1996) Macromolecules, 29, pp. 478-480; Sauvage, J.P., Collin, J.-P., Chambron, J.-C., Guillerez, S., Coudret, C., (1994) Chem. Rev., 94, pp. 993-1019; Chiper, M., Meier, M.A.R., Wouters, D., Hoeppener, S., Fustin, C.-A., Gohy, J.-F., Schubert, U.S., (2008) Macromolecules, 41, pp. 2771-2777; Nuckolls, C., Katz, T.J., Katz, G., Collings, P.J., Castellanos, L., (1999) J. Am. Chem. Soc., 121, pp. 79-88; Brunsveld, L., Meijer, E.W., Prince, R.B., Moore, J.S., (2001) J. Am. Chem. Soc., 123, pp. 7978-7984; Yamaguchi, N., Gibson, H.W., (1999) Angew. Chem., Int. Ed., 38, pp. 143-147; Ashton, P.R., Campbell, P.J., Chrystal, E.J.T., Glink, P.T., Menzer, S., Philp, D., Spencer, N., Williams, D.J., (1995) Angew. Chem., Int. Ed. Engl., 34, pp. 1865-1869; Fox, J.D., Rowan, S.J., (2009) Macromolecules, 42, pp. 6823-6835; Brunsveld, L., Folmer, B.J.B., Meijer, E.W., Sijbesma, R.P., (2001) Chem. Rev., 101, pp. 4071-4097; De Greef, T.F.A., Smulders, M.M.J., Wolffs, M., Schenning, A.P.H.J., Sijbesma, R.P., Meijer, E.W., (2009) Chem. Rev., 109, pp. 5687-5754; Ikkala, O., Brinke, G., (2002) Science, 295, p. 2407; Ambade, A.V., Burd, C., Higley, M.N., Nair, K.P., Weck, M., (2009) Chem.-Eur. J., 15, pp. 11904-11911; Yang, S.K., Ambade, A.V., Weck, M., (2009) Chem.-Eur. J., 15, pp. 6605-6611; South, C.R., Burd, C., Weck, M., (2007) Acc. Chem. Res., 40, pp. 63-74; Binder, W.B., Kunz, M.J., Kluger, C., Hayn, G., Saf, R., (2004) Macromolecules, 37, pp. 1749-1759; Burd, C., Weck, M., (2005) Macromolecules, 38, pp. 7225-7230; Binder, W.H., Bernstorff, S., Kluger, C., Petraru, L., Kunz, M.J., (2005) Adv. Mater., 17, pp. 2824-2828; Lu, D., Wang, Y., Wu, T., Tao, K., An, L., Bai, R., (2008) J. Polym. Sci., Part A: Polym. Chem., 46, pp. 5805-5815; Huang, F., Nagvekar, D.S., Slebodnick, S., Gibson, H.W., (2005) J. Am. Chem. Soc., 127, pp. 484-485; Ambade, A.V., Yang, S.K., Weck, M., (2009) Angew. Chem., Int. Ed., 48, pp. 2894-2898; Berda, E.B., Foster, J.E., Meijer, E.W., (2010) Macromolecules, 43, pp. 1430-1437; Sontjens, S.H.M., Renken, R.A.E., Van Gemert, G.M.L., Engels, T.A.P., Bosman, A.V., Janssen, H.M., Govaert, L.E., Baaijens, F.P.T., (2008) Macromolecules, 41, pp. 5703-5708; Chen, S., Bertrand, A., Chang, X., Alcouffe, P., Ladaviere, C., Gerard, J.-F., Lortie, F., Bernard, J., (2010) Macromolecules, 43, pp. 5981-5988; Yang, X., Hua, F., Yamato, K., Ruckenstein, E., Gong, B., Kim, W., Ryu, C.Y., (2004) Angew. Chem., Int. Ed., 43, pp. 6471-6474; Feldman, K.E., Kade, M.J., De Greef, T.F.A., Meijer, E.W., Kramer, E.J., Hawker, C.J., (2008) Macromolecules, 41, pp. 4694-4700; Altintas, O., Yilmaz, I., Hizal, G., Tunca, U., (2006) J. Polym. Sci., Part A: Polym. Chem., 44, pp. 3242-3249; Celiz, A.D., Scherman, O.A., (2008) Macromolecules, 41, pp. 4115-1119; Lohmeijer, B.G.G., Schubert, U.S., (2002) Angew. Chem., Int. Ed., 41, pp. 3825-3829; Van Beek, D.J.M., Gillissen, M.A.J., Van As, B.A.C., Palmans, A.R.A., Sijbesma, R.P., (2007) Macromolecules, 40, pp. 6340-6348; Yang, S.K., Ambade, A.V., Weck, M., (2010) J. Am. Chem. Soc., 132, pp. 1637-1645; Todd, E.M., Zimmerman, S.C., (2007) J. Am. Chem. Soc., 129, pp. 14534-14535; Likhitsup, A., Yu, S., Ng, Y.-H., Chai, C.L.L., Tam, E.K.W., (2009) Chem. Commun., pp. 4070-4072; Shen, Y., Tang, H., Ding, S., (2004) Prog. Polym. Sci., 29, pp. 1053-1078; Bernard, J., Lortie, F., Fenet, B., (2009) Macromol. Rapid Commun., 30, pp. 83-88; Altintas, O., Gerstel, P., Dingenouts, N., Barner-Kowollik, C., (2010) Chem. Commun., 46, pp. 6291-6293; Kolb, H.C., Finn, M.G., Sharpless, K.B., (2001) Angew. Chem., Int. Ed., 40, pp. 2004-2021; Chang, S.K., Hamilton, A.D., (1988) J. Am. Chem. Soc., 110, pp. 1318-1319; Ihre, H., Hult, A., Frechet, J.M.J., Gitsov, I., (1998) Macromolecules, 31, pp. 4061-4068; Altintas, O., Yankul, B., Hizal, G., Tunca, U., (2006) J. Polym. Sci., Part A: Polym. Chem., 44, pp. 6458-6465; Berl, V., Schmutz, M., Krische, M.J., Khoury, R.G., Lehn, J.M., (2002) Chem.-Eur. J., 8, pp. 1227-1244
Keywords: Ambient temperatures, Azide-alkyne cycloaddition, Binding motif, Copper catalyzed, Cyanuric acids, Functionalized, Functionalized poly(styrene), H-bonding, Hamiltons, High yield, Homopolymers, Methylene chloride, Miktoarm star polymers, Polymer segments, Precursor polymers, Recognition units, Star polymers, Supramolecular polymers, Acetylene, Acrylic monomers, Atom transfer radical polymerization, Block copolymers, Deuterium, Dichloromethane, Esters, Free radical reactions, Gel permeation chromatography, Organic polymers, Size exclusion chromatography, Stars, Styrene, Supramolecular chemistry, Temperature, Functional polymers
DOI: 10.1039/c0py00395f
ISSN: 17599954
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 05 Oct 2016 05:20

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