Kinetic and mechanistic similarities between reversible addition fragmentation chain transfer intermediate and acrylate midchain radicals

Barner-Kowollik, C. & Junkers, T. (2011) Kinetic and mechanistic similarities between reversible addition fragmentation chain transfer intermediate and acrylate midchain radicals. Journal of Polymer Science, Part A: Polymer Chemistry, 49(5).

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Abstract

This contribution highlights the mechanistic and kinetic similarities as well as differences between midchain radicals occurring in both acrylate free radical polymerization as well as reversible addition fragmentation chain transfer mediated processes. © 2011 Wiley Periodicals, Inc.

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11 citations in Web of Science®

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ID Code: 99265
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :11
Export Date: 5 September 2016
CODEN: JPACE
Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Karlsruhe Institute of Technology (KIT), Institut für Technische Chemie und Polymerchemie, Engesserstr. 18, 76128 Karlsruhe, Germany; email: christopher.barner-kowollik@kit.edu
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Keywords: acrylate free radical polymerization, kinetics (polym.), macromonomers, midchain radicals (MCRs), reversible addition fragmentation chain transfer (RAFT), Macro-monomers, Mid-chain radicals, Reversible addition fragmentation chain transfer, Atom transfer radical polymerization, Free radicals, Monomers, Polymers, Free radical polymerization
DOI: 10.1002/pola.24546
ISSN: 0887624X
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 05 Oct 2016 04:50

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