Rapid UV light-triggered macromolecular click conjugations via the use of o-quinodimethanes

Gruendling, T., Oehlenschlaeger, K. K., Frick, E., Glassner, M., Schmid, C., & Barner-Kowollik, C. (2011) Rapid UV light-triggered macromolecular click conjugations via the use of o-quinodimethanes. Macromolecular Rapid Communications, 32(11).

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Shining a light on click chemistry: The use of UV-radiation as trigger signal provides a facile means to obtain spatial and temporal control over polymer conjugation reactions in addition to providing a further means of achieving orthogonality in click transformations. In the current contribution, UV-radiation was employed to induce a highly efficient Diels-Alder conjugation of polymeric building blocks via the photo-induced in situ formation of highly reactive cis-dienes from a 2-methylbenzophenone precursor. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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ID Code: 99272
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :40
Export Date: 5 September 2016
Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76128 Karlsruhe, Germany; email: christopher.barner-kowollik@kit.edu
Chemicals/CAS: Benzophenones; Macromolecular Substances; Organometallic Compounds; Polymers
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Keywords: diblock copolymer, electrospray ionization mass spectrometry (SEC/ESI-MS), ortho-quinodimethanes, photo Diels-Alder, photo-conjugation, Block copolymers, Electrospray ionization, Mass spectrometry, Olefins, Polymers, benzophenone derivative, organometallic compound, polymer, article, chemistry, click chemistry, electrospray mass spectrometry, macromolecule, molecular weight, photochemistry, polymerization, synthesis, temperature, ultraviolet radiation, Benzophenones, Macromolecular Substances, Organometallic Compounds, Photochemical Processes, Spectrometry, Mass, Electrospray Ionization, Ultraviolet Rays
DOI: 10.1002/marc.201100159
ISSN: 10221336
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 05 Oct 2016 03:04

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