Constructing star polymers via modular ligation strategies

Altintas, O., Vogt, A. P., Barner-Kowollik, C., & Tunca, U. (2012) Constructing star polymers via modular ligation strategies. Polymer Chemistry, 3(1).

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Abstract

Branched polymers result in a more compact structure in comparison to linear polymers of identical molecular weight, due to their high segment density which affects the crystalline, mechanical, and viscoelastic properties of the polymer. Star polymers constitute the simplest form of branched macromolecules where all of the chains - or arm segments - of one macromolecule are linked to a centre defined as the core. Over recent years, modular ligation reactions - some of which adhere to click criteria - have enabled the synthesis of a variety of star polymers via efficient polymer-polymer conjugations. While the modified Huisgen [3 + 2] dipolar copper catalyzed azide and alkyne cycloaddition (CuAAC) has been widely employed for macromolecular star synthesis, Diels-Alder and hetero Diels-Alder reactions offer alternative pathways which allow for similarly efficient macromolecular conjugations. Moreover, combinations of these protocols afford the synthesis of more complex star polymer structures which previously had not been achievable.

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ID Code: 99294
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :92
Export Date: 5 September 2016
Correspondence Address: Barner-Kowollik, C.; Preparative Macromolecular Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76128 Karlsruhe, Germany; email: christopher.barner-kowollik@kit.edu
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Keywords: Branched macromolecules, Branched Polymer, Compact structures, Copper catalyzed, Diels-Alder, Hetero Diels-Alder reaction, High segment density, Ligation reactions, Linear polymers, Star polymers, Star-polymer structure, Viscoelastic properties, Acetylene, Cycloaddition, Macromolecules, Mechanical properties, Stars, Polymers
DOI: 10.1039/c1py00249j
ISSN: 17599954
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 04 Oct 2016 02:53

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