Interpolymer radical coupling: A toolbox complementary to controlled radical polymerization

Debuigne, A., Hurtgen, M., Detrembleur, C., Jérôme, C., Barner-Kowollik, C., & Junkers, T. (2012) Interpolymer radical coupling: A toolbox complementary to controlled radical polymerization. Progress in Polymer Science, 37(7).

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Abstract

The current review focuses on the relevance and practical benefit of interpolymer radical coupling methods. The latter are developing rapidly and constitute a perfectly complementary macromolecular engineering toolbox to the controlled radical polymerization techniques (CRP). Indeed, all structures formed by CRP are likely to be prone to radical coupling reactions, which multiply the available synthetic possibilities. Basically, the coupling systems can be divided in two main categories. The first one, including the atom transfer radical coupling (ATRC), silane radical atom abstraction (SRAA) and cobalt-mediated radical coupling (CMRC), relies on the recombination of macroradicals produced from a dormant species. The second one, including atom transfer nitroxide radical coupling (ATNRC), single electron transfer nitroxide radical coupling (SETNRC), enhanced spin capturing polymerization (ESCP) and nitrone/nitroso mediated radical coupling (NMRC), makes use of a radical scavenger in order to promote the conjugation of the polymer chains. More than a compilation of macromolecular engineering achievements, the present review additionally aims to emphasize the particularities, synthetic potential and present limitations of each system. © 2012 Elsevier Ltd. All rights reserved.

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ID Code: 99302
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :35
Export Date: 5 September 2016
CODEN: PRPSB
Correspondence Address: Debuigne, A.; Center for Education and Research on Macromolecules (CERM), Chemistry Department, University of Liege, Sart-Tilman, 4000 Liege, Belgium; email: adebuigne@ulg.ac.be
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Keywords: Block copolymers, Controlled/living radical polymerization, Macrocycles, Radical coupling, Radical reactions, Telechelic polymers, Atom transfer radical polymerization, Cobalt, Macromolecules, Polymerization, Polymers, Reaction kinetics, Free radical reactions
DOI: 10.1016/j.progpolymsci.2012.01.003
ISSN: 00796700
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 04 Oct 2016 03:35

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