Radical addition fragmentation chain transfer (RAFT) polymerization of ferrocenyl (Meth)acrylates

Herfurth, C., Voll, D., Buller, J., Weiss, J., Barner-Kowollik, C., & Laschewsky, A. (2012) Radical addition fragmentation chain transfer (RAFT) polymerization of ferrocenyl (Meth)acrylates. Journal of Polymer Science, Part A: Polymer Chemistry, 50(1).

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Abstract

We report on the controlled free radical homopolymerization of 1-ferrocenylethyl acrylate as well as of three new ferrocene bearing monomers, namely 4-ferrocenylbutyl acrylate, 2-ferrocenylamido-2-methylpropyl acrylate, and 4-ferrocenylbutyl methacrylate, by the RAFT technique. For comparison, the latter monomer was polymerized using ATRP, too. The ferrocene containing monomers were found to be less reactive than their analogues free of ferrocene. The reasons for the low polymerizability are not entirely clear. As the addition of free ferrocene to the reaction mixture did not notably affect the polymerizations, sterical hindrance by the bulky ferrocene moiety fixed on the monomers seems to be the most probable explanation. Molar masses found for 1-ferrocenylethyl acrylate did not exceed 10,000 g mol-1, while for 4-ferrocenylbutyl (meth)acrylate molar masses of 15,000 g mol-1 could be obtained. With PDIs as low as 1.3 in RAFT polymerization of the monomers, good control over the polymerization was achieved. © 2011 Wiley Periodicals, Inc.

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ID Code: 99312
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :18
Export Date: 5 September 2016
CODEN: JPACE
Correspondence Address: Laschewsky, A.; Institut für Chemie, Universität Potsdam, Karl-Liebknecht-Str. 24-25, 14476 Potsdam-Golm, Germany; email: laschews@rz.uni-potsdam.de
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Keywords: ferrocene, living radical polymerization (LRP), monomers, radical addition fragmentation chain transfer (RAFT), radical polymerization, redox polymers, synthesis, Chain transfer, Ferrocene moiety, Ferrocenes, Ferrocenyl, Most probable explanation, Radical addition, RAft polymerization, Reaction mixture, Atom transfer radical polymerization, Free radicals, Homopolymerization, Iron compounds, Living polymerization, Organometallics, Polymers, Synthesis (chemical), Free radical polymerization
DOI: 10.1002/pola.24994
ISSN: 0887624X
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 04 Oct 2016 04:58

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