Supramolecular three-armed star polymers via cyclodextrin host-guest self-assembly

Schmidt, B. V. K. J., Rudolph, T., Hetzer, M., Ritter, H., Schacher, F. H., & Barner-Kowollik, C. (2012) Supramolecular three-armed star polymers via cyclodextrin host-guest self-assembly. Polymer Chemistry, 3(11).

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Abstract

Three-armed star polymers with a cyclodextrin core and polyacrylamide arms were prepared via inclusion complex formation. A novel adamantyl-functionalized chain transfer agent was utilized in the reversible addition-fragmentation chain transfer (RAFT) polymerization of N,N-dimethylacrylamide and N,N-diethylacrylamide to afford guest-functionalized polymers. In combination with a three-pronged β-cyclodextrin core, supramolecular self-assembly was exploited for the formation of star-shaped architectures. This was demonstrated via a combination of dynamic light scattering (DLS) and 2D rotating frame nuclear Overhauser effect spectroscopy (ROESY) in D 2O. Furthermore, turbidity measurements in the case of PDEAAm showed a rise in the LCST of the system. The complex formation was shown to be reversible, as DLS at elevated temperatures (70 °C) indicated a complete disassembly of the star polymers. © 2012 The Royal Society of Chemistry.

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ID Code: 99323
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :39
Export Date: 5 September 2016
Correspondence Address: Ritter, H.; Lehrstuhl für Präparative Polymerchemie, Institut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine Universität, Universitätsstrasse 1, Geb. 26.33.00, 40225 Düsseldorf, Germany; email: h.ritter@uni-duesseldorf.de
References: Higashihara, T., Hayashi, M., Hirao, A., (2011) Prog. Polym. Sci., 36, pp. 323-375; Khanna, K., Varshney, S., Kakkar, A., (2010) Polym. Chem., 1, pp. 1171-1185; Inoue, K., (2000) Prog. Polym. Sci., 25, pp. 453-571; Kreutzer, G., Ternat, C., Nguyen, T.Q., Plummer, C.J.G., Månson, J.-A.E., Castelletto, V., Hamley, I.W., Klok, H.-A., (2006) Macromolecules, 39, pp. 4507-4516; Liu, J., Duong, H., Whittaker, M.R., Davis, T.P., Boyer, C., (2012) Macromol. Rapid Commun., 33, pp. 760-766; Chen, L., Li, P., Tong, H., Xie, Z., Wang, L., Jing, X., Wang, F., (2012) J. Polym. Sci., Part A: Polym. Chem., 50, pp. 2854-2862; Kanaoka, S., Sawamoto, M., Higashimura, T., (1991) Macromolecules, 24, pp. 2309-2313; Schlaad, H., Diehl, C., Gress, A., Meyer, M., Demirel, A.L., Nur, Y., Bertin, A., (2010) Macromol. Rapid Commun., 31, pp. 511-525; Hirano, T., Yoo, H.S., Ozama, Y., Abou El-Magd, A., Sugiyama, K., Hirao, A., (2010) J. Inorg. Organomet. Polym. Mater., 20, pp. 445-456; Roovers, J.E.L., Bywater, S., (1974) Macromolecules, 7, pp. 443-449; Hawker, C.J., Bosman, A.W., Harth, E., (2001) Chem. Rev., 101, pp. 3661-3688; Braunecker, W.A., Matyjaszewski, K., (2007) Prog. Polym. Sci., 32, pp. 93-146; Chiefari, J., Chong, Y.K., Ercole, F., Krstina, J., Jeffery, J., Le, T.P.T., Mayadunne, R.T.A., Thang, S.H., (1998) Macromolecules, 31, pp. 5559-5562; Barner-Kowollik, C., (2008) Handbook of RAFT-Polymerization, , ed., Wiley-VCH, Weinheim, Germany; Jankova, K., Bednarek, M., Hvilsted, S., (2005) J. Polym. Sci., Part A: Polym. Chem., 43, pp. 3748-3759; Barner-Kowollik, C., Davis, T.P., Stenzel, M.H., (2006) Aust. J. Chem., 59, pp. 719-727; Hawker, C.J., (1995) Angew. Chem., Int. Ed. Engl., 34, pp. 1456-1459; Altintas, O., Vogt, A.P., Barner-Kowollik, C., Tunca, U., (2012) Polym. Chem., 3, pp. 34-45; Barner-Kowollik, C., Du Prez, F.E., Espeel, P., Hawker, C.J., Junkers, T., Schlaad, H., Van Camp, W., (2011) Angew. Chem., Int. Ed., 50, pp. 60-62; Gao, H., Matyjaszewski, K., (2006) Macromolecules, 39, pp. 4960-4965; Fijten, M.W.M., Haensch, C., Van Lankvelt, B.M., Hoogenboom, R., Schubert, U.S., (2008) Macromol. Chem. Phys., 209, pp. 1887-1895; Chan, J.W., Yu, B., Hoyle, C.E., Lowe, A.B., (2008) Chem. Commun., pp. 4959-4961; Inglis, A.J., Sinnwell, S., Stenzel, M.H., Barner-Kowollik, C., (2009) Angew. Chem., Int. Ed., 48, pp. 2411-2414; Iskin, B., Yilmaz, G., Yagci, Y., (2011) Polym. Chem., 2, pp. 2865-2871; Bernard, J., Lortie, F., Fenet, B., (2009) Macromol. Rapid Commun., 30, pp. 83-88; Altintas, O., Muller, T., Lejeune, E., Plietzsch, O., Bräse, S., Barner-Kowollik, C., (2012) Macromol. Rapid Commun., 33, pp. 977-983; Likhitsup, A., Yu, S., Ng, Y.-H., Chai, C.L.L., Tam, E.K.W., (2009) Chem. Commun., pp. 4070-4072; Wu, X., Fraser, C.L., (2000) Macromolecules, 33, pp. 7776-7785; Schubert, U.S., Heller, M., (2001) Chem.-Eur. J., 7, pp. 5252-5259; Gadwal, I., De, S., Stuparu, M.C., Amir, R.J., Jang, S.G., Khan, A., (2012) J. Polym. Sci., Part A: Polym. Chem., 50, pp. 1844-1850; Huang, F., Nagvekar, D.S., Slebodnick, C., Gibson, H.W., (2004) J. Am. Chem. Soc., 127, pp. 484-485; Schmidt, B.V.K.J., Hetzer, M., Ritter, H., Barner-Kowollik, C., (2012) Polym. Chem., , 10.1039/C2PY20214J; Davis, M.E., (2009) Mol. Pharmaceutics, 6, pp. 659-668; Yhaya, F., Lim, J., Kim, Y., Liang, M., Gregory, A.M., Stenzel, M.H., (2011) Macromolecules, 44, pp. 8433-8445; Zhou, J., Ritter, H., (2010) Polym. Chem., 1, pp. 1552-1559; Schmidt, B.V.K.J., Hetzer, M., Ritter, H., Barner-Kowollik, C., (2011) Macromolecules, 44, pp. 7220-7232; Köllisch, H.S., Barner-Kowollik, C., Ritter, H., (2009) Chem. Commun., pp. 1097-1099; Ritter, H., Mondrzik, B.E., Rehahn, M., Gallei, M., (2010) Beilstein J. Org. Chem., 6, p. 60; Ding, L., Li, Y., Deng, J., Yang, W., (2011) Polym. Chem., 2, pp. 694-701; Ohno, K., Wong, B., Haddleton, D.M., (2001) J. Polym. Sci., Part A: Polym. Chem., 39, pp. 2206-2214; Stenzel, M.H., Davis, T.P., (2002) J. Polym. Sci., Part A: Polym. Chem., 40, pp. 4498-4512; Miura, Y., Narumi, A., Matsuya, S., Satoh, T., Duan, Q., Kaga, H., Kakuchi, T., (2005) J. Polym. Sci., Part A: Polym. Chem., 43, pp. 4271-4279; Zhang, Z.-X., Liu, X., Xu, F.J., Loh, X.J., Kang, E.-T., Neoh, K.-G., Li, J., (2008) Macromolecules, 41, pp. 5967-5970; Zhang, Z.-X., Liu, K.L., Li, J., (2011) Macromolecules, 44, pp. 1182-1193; Yu, Z., Sawkar, A.R., Whalen, L.J., Wong, C.-H., Kelly, J.W., (2006) J. Med. Chem., 50, pp. 94-100; Skey, J., O'Reilly, R.K., (2008) Chem. Commun., pp. 4183-4185; Amajjahe, S., Choi, S., Munteanu, M., Ritter, H., (2008) Angew. Chem., Int. Ed., 47, pp. 3435-3437; Dong, R., Liu, Y., Zhou, Y., Yan, D., Zhu, X., (2011) Polym. Chem., 2, pp. 2771-2774; Kuo, C., Provder, T., Koehler, M.E., (1991) Int. GPC Symposium Proceeding, pp. 147-159. , in; Rekharsky, M.V., Inoue, Y., (1998) Chem. Rev., 98, pp. 1875-1918; Kujawa, P., Winnik, F.M., (2001) Macromolecules, 34, pp. 4130-4135; Mao, H., Li, C., Zhang, Y., Furyk, S., Cremer, P.S., Bergbreiter, D.E., (2004) Macromolecules, 37, pp. 1031-1036; Wang, X., Wu, C., (1999) Macromolecules, 32, pp. 4299-4301; Gan, L.H., Cai, W., Tam, K.C., (2001) Eur. Polym. J., 37, pp. 1773-1778; Kujawa, P., Segui, F., Shaban, S., Diab, C., Okada, Y., Tanaka, F., Winnik, F.M., (2005) Macromolecules, 39, pp. 341-348; Schneider, H.-J., Hacket, F., Rüdiger, V., Ikeda, H., (1998) Chem. Rev., 98, pp. 1755-1786; Liu, H., Zhang, Y., Hu, J., Li, C., Liu, S., (2009) Macromol. Chem. Phys., 210, pp. 2125-2137
Keywords: Chain transfer agents, Complex formations, Cyclodextrin core, Elevated temperature, Host-guests, Inclusion complex, N ,n-dimethylacrylamide, Reversible addition-fragmentation chain transfer polymerization, Rotating frame nuclear Overhauser effect spectroscopy, Star polymers, Supramolecular self-assemblies, Turbidity measurements, Acrylic monomers, Dynamic light scattering, Self assembly, Supramolecular chemistry, Turbidity, Polymers
DOI: 10.1039/c2py20293j
ISSN: 17599954
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 04 Oct 2016 23:56

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