A qualitative and quantitative post-mortem analysis: Studying free-radical initiation processes via soft ionization mass spectrometry

Voll, D., Junkers, T., & Barner-Kowollik, C. (2012) A qualitative and quantitative post-mortem analysis: Studying free-radical initiation processes via soft ionization mass spectrometry. Journal of Polymer Science, Part A: Polymer Chemistry, 50(14).

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Abstract

The current article contains a review of the electrospray ionization-mass spectrometry characterization of polymers prepared via thermal- and photoinitiation processes. The used analysis method permits direct access to detailed endgroup information. For a qualitative and quantitative endgroup analysis, sophisticated methods have been developed which provide a detailed image of the incorporation propensity of thermally as well as photolytically generated radicals at the polymer chain termini. Such a post-mortem analysis of polymeric materials specifically allows for the quantification of the ability of radical fragments to initiate polymerization processes. Herein, the most recent progress in the field of mass spectrometric radical reactivity mapping is outlined and open questions as well as future directions are discussed. © 2012 Wiley Periodicals, Inc.

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ID Code: 99327
Item Type: Journal Article
Refereed: Yes
Additional Information: Cited By :13
Export Date: 5 September 2016
CODEN: JPACE
Correspondence Address: Junkers, T.; Institute for Materials Research (IMO), Polymer Reaction Design Group, Universiteit Hasselt, Agoralaan, Gebouw D, BE-3590 Diepenbeek, Belgium; email: thomas.junkers@uhasselt.be
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Keywords: initiators, laser-induced polymers, mass spectrometry, photopolymerization, radical polymerization, size exclusion chromatography (SEC), thermal initiators, Analysis method, Electrospray ionization mass spectrometry, End groups, End-group analysis, Initiation process, Photoinitiation, Polymer chains, Polymerization process, Postmortem analysis, Recent progress, Soft ionization, Electrospray ionization, Free radical polymerization, Initiators (explosives), Polymerization
DOI: 10.1002/pola.26076
ISSN: 0887624X
Divisions: Current > Schools > School of Chemistry, Physics & Mechanical Engineering
Current > Institutes > Institute for Future Environments
Current > QUT Faculties and Divisions > Science & Engineering Faculty
Deposited On: 22 Sep 2016 04:50
Last Modified: 04 Oct 2016 02:22

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